Ritter reaction on terpenoids. IV. Remarkable tendency to produce 3-aza-bicyclo[3.3.1]non-2-ene systems from mono and sesquiterpenes

Reaction of cyclic and acyclic monoterpenes with acetonitrile under Ritter type conditions was investigated. An unusual tendency to obtain racemic 8-acetamido-2,4,4,8-tetramethyl-3-aza-bicyclo [3.3.1] non-2-ene perchlorate was observed in all cases regardless of the starting terpene. It is worthy to...

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Autores principales: Rodriguez, J.B., Gros, E.G., Caram, J.A., Marschoff, C.M.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404039_v36_n43_p7825_Rodriguez
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