The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce...

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Detalles Bibliográficos
Autores principales:	Doctorovich, F., Trápani, C.
Formato:	JOUR
Materias:	Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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