Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate

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The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all t...

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Detalles Bibliográficos
Autores principales: Perec, M., Baggio, R., Garland, M.T.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_01082701_v55_n6_p858_Perec
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spelling todo:paper_01082701_v55_n6_p858_Perec2023-10-03T14:57:48Z Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate Perec, M. Baggio, R. Garland, M.T. The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
format JOUR
author Perec, M.
Baggio, R.
Garland, M.T.
spellingShingle Perec, M.
Baggio, R.
Garland, M.T.
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
author_facet Perec, M.
Baggio, R.
Garland, M.T.
author_sort Perec, M.
title Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_short Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_fullStr Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full_unstemmed Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_sort hexakis(imidazole-n3)nickel(ii) oxydiacetate ethanol solvate
url http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
work_keys_str_mv AT perecm hexakisimidazolen3nickeliioxydiacetateethanolsolvate
AT baggior hexakisimidazolen3nickeliioxydiacetateethanolsolvate
AT garlandmt hexakisimidazolen3nickeliioxydiacetateethanolsolvate
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