Analysis of the phosphorus lone-pair orientational effect on 31P13C couplings in 7-(phosphamethyl)norbornene
An IPPP-INDO analysis of PC couplings is carried out in 7-(phosphamethyl) norbornene for the anti and syn conformations. A strong orientational effect of the P lone pair is expected to be responsible for the differences in the coupling values between conformations. Total couplings are decomposed int...
Guardado en:
| Autores principales: | Aucar, G.A., Giribet, C.G., De Azúa, M.C.R., Diz, A.C., Contreras, R.H. |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01661280_v164_n1-2_p1_Aucar |
| Aporte de: |
Ejemplares similares
-
Analysis of the phosphorus lone-pair orientational effect on 31P13C couplings in 7-(phosphamethyl)norbornene
por: Aucar, G.A
Publicado: (1988) -
Analysis of the phosphorus lone-pair orientational effect on 31P13C couplings in 7-(phosphamethyl)norbornene
por: Aucar, Gustavo A., et al.
Publicado: (1988) -
Quantum chemical analysis of the orientational lone-pair effect on spin-spin coupling constants
por: Contreras, R.H., et al. -
Polarization propagator analysis of the through space transmission of spin-spin coupling constants by overlap of lone pairs
por: Giribet, C.G., et al. -
Theoretical IPPP analysis of 13C‐31 P through‐space indirect couplings in phosphorus‐substituted alkenes
por: Diz, A.C., et al.