Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems.
The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex for...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz |
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todo:paper_01677322_v38_n3-4_p225_RebolloPaz2023-10-03T15:05:18Z Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. Rebollo Paz, M.B. Buep, A.H. Baron, M. The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex formation is introduced. As a result the range of validity of the model extends into the non-dilute region and up to the limit where complexes other than 1:1 appear. These changes allow also to calculate the equilibrium constant (K) for the 1:1 complex from dielectric measurements in the dilute region. The values are in good agreement with those found in the literature. © 1988. Fil:Rebollo Paz, M.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Buep, A.H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baron, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz |
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Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The dielectric behavior of polar non polar liquid systems is treated as the result of associations through changes in the model proposed by Mechetti and Barón for very dilute solutions. The existence of a 1:1 interaction product (or complex) is assumed and the equilibrium constant (K) of complex formation is introduced. As a result the range of validity of the model extends into the non-dilute region and up to the limit where complexes other than 1:1 appear. These changes allow also to calculate the equilibrium constant (K) for the 1:1 complex from dielectric measurements in the dilute region. The values are in good agreement with those found in the literature. © 1988. |
| format |
JOUR |
| author |
Rebollo Paz, M.B. Buep, A.H. Baron, M. |
| spellingShingle |
Rebollo Paz, M.B. Buep, A.H. Baron, M. Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| author_facet |
Rebollo Paz, M.B. Buep, A.H. Baron, M. |
| author_sort |
Rebollo Paz, M.B. |
| title |
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| title_short |
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| title_full |
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| title_fullStr |
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| title_full_unstemmed |
Dielectric properties of binary systems 8. Improved model for alcohol/non polar systems. |
| title_sort |
dielectric properties of binary systems 8. improved model for alcohol/non polar systems. |
| url |
http://hdl.handle.net/20.500.12110/paper_01677322_v38_n3-4_p225_RebolloPaz |
| work_keys_str_mv |
AT rebollopazmb dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems AT buepah dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems AT baronm dielectricpropertiesofbinarysystems8improvedmodelforalcoholnonpolarsystems |
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1807322281880322048 |