Transmission mechanisms of four-bond 19F19F coupling constants in fluoropropenes: A theoritical and experimental study

Four-bond FF couplings were measured in cis- and trans-isomers of 1,3-diflouro- and 1,3,3,3-tetraflouro-propene. These couplings show a pronounced depedence on the member of flourines attached to the sp3 carbon atom. This dependence is much larger for the cis-isomers than for the trans ones. A theor...

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Autores principales: Natiello, M.A., Contreras, R.H., Gavarini, H.O., Rae, I.D.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03010104_v98_n2_p279_Natiello
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