Molecular structure effects on the kinetics of hydroxyl radical addition to azo dyes

The effect of the molecular structure of azobenzene and related azo dyes on their reactivity towards ·OH radicals in water was investigated by performing ultrasonic irradiation experiments on their aqueous solutions and density functional theory (DFT) calculations. Sonolysis of azobenzene, methyl or...

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Detalles Bibliográficos
Autores principales: Destaillats, H., Turjanski, A.G., Estrin, D.A., Hoffmann, M.R.
Formato: JOUR
Materias:
Azo dyes
Hydroxyl radical addition
Kinetics
Molecular structure
Addition reactions
Carboxylic acids
Free radicals
Hydrogen bonds
Isomers
Photodegradation
Probability density function
Rate constants
Solutions
Thermodynamics
Ultrasonic effects
Non-buffered solutions
Solvation
Sonolysis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_08943230_v15_n5_p287_Destaillats
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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