Effect of Keggin polyoxometalate on Cu(ii) speciation and its role in the assembly of Cu3(BTC)2 metal-organic framework

HKUST-1 is one of the popular metal-organic frameworks (MOFs). The formation of this MOF is significantly accelerated by adding Keggin polyoxometalate anions to the synthesis solution. In this paper the chemistry behind this observation was investigated. Upon addition of Keggin type H 3PW12O40 heter...

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Detalles Bibliográficos
Autores principales:	Bajpe, S.R., Breynaert, E., Mustafa, D., Jobbágy, M., Maes, A., Martens, J.A., Kirschhock, C.E.A.
Formato:	JOUR
Materias:	Acidic conditions Heteropoly acids Keggin ions Keggin polyoxometalate Keggin-type Metal organic framework Paddle wheels PH measurements Room temperature Synthesis solution XANES measurements Ethanol Hydrolysis Ions Oxides
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_09599428_v21_n26_p9768_Bajpe
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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