A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles

The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylen...

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Autores principales: Edelsztein, V.C., Jares-Erijman, E.A., Müllen, K., Di Chenna, P.H., Spagnuolo, C.C.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09599428_v22_n41_p21857_Edelsztein
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Sumario:The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylene fluorophore. The compatibility of the photochromic compound in this medium and the non-destructive readout capability were demonstrated. The dye doped organogel was further used as a template and an innovative method was employed to grow fluorescent silica spherical nanoparticles with physically and chemically admixed perylene dye. © 2012 The Royal Society of Chemistry.