Lubricants from chemically modified vegetable oils

This work reports laboratory results obtained from the production of polyols with branched ether and ester compounds from epoxidized vegetable oils pertaining to annual, temperate climate crops (soybean, sunflower and high-oleic sunflower oils), focusing on their possible use as components of lubric...

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Autores principales:	Campanella, A., Rustoy, E., Baldessari, A., Baltanás, M.A.
Formato:	JOUR
Materias:	Lubricants Oxirane ring-opening Polyol derivatives Vegetable oils Acid media Aliphatic alcohol Base stock Chemically modified Epoxidized vegetable oil Experimental data Glacial acetic acid Long-term storage Oleic sunflower Opening reactions Organic phase Polyols Rheological technique Short reaction time Synthesis temperatures Temperate climate Aromatic hydrocarbons Chemical modification Climatology Esters Ethanol Ethers Lubricating oils Methanol Synthesis (chemical) acetic acid alcohol alkanol epoxide ester derivative ether derivative lubricating agent methanol polyol sunflower oil vegetable oil nuclear magnetic resonance rheology viscosity article chemical modification chemical reaction priority journal synthesis temperature Computer Simulation Lubrication Materials Testing Models, Chemical Plant Oils Viscosity Glycine max Helianthus
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_09608524_v101_n1_p245_Campanella
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_09608524_v101_n1_p245_Campanella
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spelling	todo:paper_09608524_v101_n1_p245_Campanella2023-10-03T15:53:53Z Lubricants from chemically modified vegetable oils Campanella, A. Rustoy, E. Baldessari, A. Baltanás, M.A. Lubricants Oxirane ring-opening Polyol derivatives Vegetable oils Acid media Aliphatic alcohol Base stock Chemically modified Epoxidized vegetable oil Experimental data Glacial acetic acid Long-term storage Oleic sunflower Opening reactions Organic phase Oxirane ring-opening Polyol derivatives Polyols Rheological technique Short reaction time Synthesis temperatures Temperate climate Aromatic hydrocarbons Chemical modification Climatology Esters Ethanol Ethers Lubricating oils Methanol Synthesis (chemical) Vegetable oils acetic acid alcohol alkanol epoxide ester derivative ether derivative lubricating agent methanol polyol sunflower oil vegetable oil acetic acid nuclear magnetic resonance rheology vegetable oil viscosity article chemical modification chemical reaction priority journal synthesis temperature viscosity Computer Simulation Lubricants Lubrication Materials Testing Models, Chemical Plant Oils Viscosity Glycine max Helianthus This work reports laboratory results obtained from the production of polyols with branched ether and ester compounds from epoxidized vegetable oils pertaining to annual, temperate climate crops (soybean, sunflower and high-oleic sunflower oils), focusing on their possible use as components of lubricant base stocks. To this end, two different opening reactions of the epoxide ring were studied. The first caused by the attack with glacial acetic acid (exclusively in a single organic phase) and the second using short-chain aliphatic alcohols, methanol and ethanol, in acid media. Both reactions proceed under mild conditions: low synthesis temperature and short reaction times and with conversions above 99%. Spectroscopic (NMR), thermal (DSC) and rheological techniques were used to characterize the oils, their epoxides and polyols, to assess the impact of the nature of the vegetable oil and the chemical modifications introduced, including long-term storage conditions. Several correlations were employed to predict the viscosity of the vegetable oils with temperature, and good agreement with the experimental data was obtained. © 2009 Elsevier Ltd. All rights reserved. Fil:Rustoy, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baldessari, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09608524_v101_n1_p245_Campanella
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Lubricants Oxirane ring-opening Polyol derivatives Vegetable oils Acid media Aliphatic alcohol Base stock Chemically modified Epoxidized vegetable oil Experimental data Glacial acetic acid Long-term storage Oleic sunflower Opening reactions Organic phase Oxirane ring-opening Polyol derivatives Polyols Rheological technique Short reaction time Synthesis temperatures Temperate climate Aromatic hydrocarbons Chemical modification Climatology Esters Ethanol Ethers Lubricating oils Methanol Synthesis (chemical) Vegetable oils acetic acid alcohol alkanol epoxide ester derivative ether derivative lubricating agent methanol polyol sunflower oil vegetable oil acetic acid nuclear magnetic resonance rheology vegetable oil viscosity article chemical modification chemical reaction priority journal synthesis temperature viscosity Computer Simulation Lubricants Lubrication Materials Testing Models, Chemical Plant Oils Viscosity Glycine max Helianthus
spellingShingle	Lubricants Oxirane ring-opening Polyol derivatives Vegetable oils Acid media Aliphatic alcohol Base stock Chemically modified Epoxidized vegetable oil Experimental data Glacial acetic acid Long-term storage Oleic sunflower Opening reactions Organic phase Oxirane ring-opening Polyol derivatives Polyols Rheological technique Short reaction time Synthesis temperatures Temperate climate Aromatic hydrocarbons Chemical modification Climatology Esters Ethanol Ethers Lubricating oils Methanol Synthesis (chemical) Vegetable oils acetic acid alcohol alkanol epoxide ester derivative ether derivative lubricating agent methanol polyol sunflower oil vegetable oil acetic acid nuclear magnetic resonance rheology vegetable oil viscosity article chemical modification chemical reaction priority journal synthesis temperature viscosity Computer Simulation Lubricants Lubrication Materials Testing Models, Chemical Plant Oils Viscosity Glycine max Helianthus Campanella, A. Rustoy, E. Baldessari, A. Baltanás, M.A. Lubricants from chemically modified vegetable oils
topic_facet	Lubricants Oxirane ring-opening Polyol derivatives Vegetable oils Acid media Aliphatic alcohol Base stock Chemically modified Epoxidized vegetable oil Experimental data Glacial acetic acid Long-term storage Oleic sunflower Opening reactions Organic phase Oxirane ring-opening Polyol derivatives Polyols Rheological technique Short reaction time Synthesis temperatures Temperate climate Aromatic hydrocarbons Chemical modification Climatology Esters Ethanol Ethers Lubricating oils Methanol Synthesis (chemical) Vegetable oils acetic acid alcohol alkanol epoxide ester derivative ether derivative lubricating agent methanol polyol sunflower oil vegetable oil acetic acid nuclear magnetic resonance rheology vegetable oil viscosity article chemical modification chemical reaction priority journal synthesis temperature viscosity Computer Simulation Lubricants Lubrication Materials Testing Models, Chemical Plant Oils Viscosity Glycine max Helianthus
description	This work reports laboratory results obtained from the production of polyols with branched ether and ester compounds from epoxidized vegetable oils pertaining to annual, temperate climate crops (soybean, sunflower and high-oleic sunflower oils), focusing on their possible use as components of lubricant base stocks. To this end, two different opening reactions of the epoxide ring were studied. The first caused by the attack with glacial acetic acid (exclusively in a single organic phase) and the second using short-chain aliphatic alcohols, methanol and ethanol, in acid media. Both reactions proceed under mild conditions: low synthesis temperature and short reaction times and with conversions above 99%. Spectroscopic (NMR), thermal (DSC) and rheological techniques were used to characterize the oils, their epoxides and polyols, to assess the impact of the nature of the vegetable oil and the chemical modifications introduced, including long-term storage conditions. Several correlations were employed to predict the viscosity of the vegetable oils with temperature, and good agreement with the experimental data was obtained. © 2009 Elsevier Ltd. All rights reserved.
format	JOUR
author	Campanella, A. Rustoy, E. Baldessari, A. Baltanás, M.A.
author_facet	Campanella, A. Rustoy, E. Baldessari, A. Baltanás, M.A.
author_sort	Campanella, A.
title	Lubricants from chemically modified vegetable oils
title_short	Lubricants from chemically modified vegetable oils
title_full	Lubricants from chemically modified vegetable oils
title_fullStr	Lubricants from chemically modified vegetable oils
title_full_unstemmed	Lubricants from chemically modified vegetable oils
title_sort	lubricants from chemically modified vegetable oils
url	http://hdl.handle.net/20.500.12110/paper_09608524_v101_n1_p245_Campanella
work_keys_str_mv	AT campanellaa lubricantsfromchemicallymodifiedvegetableoils AT rustoye lubricantsfromchemicallymodifiedvegetableoils AT baldessaria lubricantsfromchemicallymodifiedvegetableoils AT baltanasma lubricantsfromchemicallymodifiedvegetableoils
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Lubricants from chemically modified vegetable oils

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