Chemoenzymatic synthesis of nitrogen polymers with biomedical applications catalyzed by lipases

The application of Candida antarctica lipase B as catalyst in the synthesis of two examples of nitrogen polymers is described. Firstly, we report a novel linear polyamidoamine oligomer, obtained by polymerization of ethyl acrylate and N-methyl-1,3-diaminopropane, catalyzed by Candida antarctica lipa...

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Detalles Bibliográficos
Autores principales: Baldessari, A., Liñares, G.G.
Formato: SER
Materias:
Aza-Michael addition and aminolysis reactions
Lipases
Nitrogen polymers
Polyamidoamine
Poly[N-(2-hydroxyethyl)-β-propylamide-g-polycaprolactone]
1,3 propanediamine
acrylic acid ethyl ester
lipase B
n methyl 1,3 diaminopropane
nitrogen
oligomer
polyamidoamine
polycaprolactone
polymer
polypropylene
triacylglycerol lipase
unclassified drug
acetylation
aminolysis
aqueous solution
biocompatibility
Burkholderia cepacia
Candida antarctica
carbon nuclear magnetic resonance
catalyst
enzyme synthesis
matrix assisted laser desorption ionization time of flight mass spectrometry
Michael addition
molecular weight
nonhuman
polymerization
proton nuclear magnetic resonance
ring opening
scanning electron microscopy
ultraviolet radiation
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_10643745_v1835_n_p359_Baldessari
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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