Strong metal-to-ligand π-backbonding weakens the N[sbnd]N bond in 2-pyridinealdazine coordinated to tetraammine-ruthenium(II)

A new mononuclear Ru(II) complex of formula [Ru(NH3)4(2-PCA)](PF6)2, (1), with 2-PCA = 2-pyridinealdazine, has been synthesized and characterized by spectroscopic and electrochemical techniques. The complete structure of (1) was determined by X-ray diffraction. A strong π-backbonding effect dπ(Ru) →...

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Detalles Bibliográficos
Autores principales: Cattaneo, M., Alborés, P., Fagalde, F., Katz, N.E.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_13877003_v80_n_p69_Cattaneo
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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