Nitrosyl-nitrite interconversion in pentacyanoruthenate(II) complexes

The nucleophilic addition of OH- to [Ru(CN)5(NO)]2- leads to the N-bonded pentacyanonitroruthenate(II) ion (λmax = 320 nm, ε = 3850 dm3 mol-1 cm-1). The stoichiometry is 2:1 ([OH-]:[Ru]) and the equilibrium formation constant is 4.4 × 106 dm6 mol-2 (25 °C, I = 1 mol dm-3). A kinetic study of the for...

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Detalles Bibliográficos
Autores principales:	Chevalier, A.A., Gentil, L.A., Olabe, J.A.
Formato:	JOUR
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_14727773_v_n8_p1959_Chevalier
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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