The reaction of 2,4-dinitrofluorobenzene with aniline, cyclohexylamine, and 1,2-diaminocyclohexanes in aprotic solvents. A new approach to the 'dimer mechanism'

The reaction of 2,4-dinitrofluorobenzene (DNF) with aniline in toluene and in chloroform at 35°C shows a third-order kinetic dependence on [amine]. In hydrogen-bond acceptor (HBA) solvents, an important rate increase, and a second-order dependence on [amine], are observed. Finally, the reaction show...

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Autores principales: Nudelman, N.S., Montserrat, J.M.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_1472779X_v_n7_p1073_Nudelman
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