Complementarity relation for irreversible processes near steady states
A relation giving a minimum for the irreversible work in quasi-equilibrium processes was derived by Sekimoto et al. [K. Sekimoto, S. Sasa, J. Phys. Soc. Japan 66 [1997] 3326] in the framework of stochastic energetics. This relation can also be written as a type of "uncertainty principle"...
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| Lenguaje: | Inglés |
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| Acceso en línea: | http://ri.agro.uba.ar/files/intranet/articulo/2013santini.pdf LINK AL EDITOR |
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| 100 | 1 | |a Santini, E. S. |9 72481 | |
| 245 | 0 | 0 | |a Complementarity relation for irreversible processes near steady states |
| 520 | |a A relation giving a minimum for the irreversible work in quasi-equilibrium processes was derived by Sekimoto et al. [K. Sekimoto, S. Sasa, J. Phys. Soc. Japan 66 [1997] 3326] in the framework of stochastic energetics. This relation can also be written as a type of "uncertainty principle" in such a way that the precise determination of the Helmholtz free energy through the observation of the work [W] requires an indefinitely large experimental time delta t. In the present article, we extend this relation to the case of quasi-steady processes by using the concept of non-equilibrium Helmholtz free energy. We give a formulation of the second law for these processes that extends that presented by Sekimoto [K. Sekimoto, Prog. Theoret. Phys. Suppl. No. 130 [1998] 17] by a term of the first order in the inverse of the experimental time. As an application of our results, two possible experimental situations are considered: stretching of a RNA molecule and the drag of a dipolar particle in the presence of a gradient of electric force. | ||
| 653 | 0 | |a FLUCTUATION PHENOMENA | |
| 653 | 0 | |a LANGEVIN EQUATION | |
| 653 | 0 | |a STOCHASTIC ENERGETICS | |
| 653 | 0 | |a THERMODYNAMICS | |
| 653 | 0 | |a COMPLEMENTARITY RELATIONS | |
| 653 | 0 | |a IRREVERSIBLE PROCESS | |
| 653 | 0 | |a PRECISE DETERMINATIONS | |
| 653 | 0 | |a QUASI-EQUILIBRIUM PROCESS | |
| 653 | 0 | |a UNCERTAINTY PRINCIPLES | |
| 653 | 0 | |a DIFFERENTIAL EQUATIONS | |
| 653 | 0 | |a FREE ENERGY | |
| 653 | 0 | |a RNA | |
| 653 | 0 | |a STOCHASTIC SYSTEMS | |
| 653 | 0 | |a STATISTICAL MECHANICS | |
| 700 | 1 | |a Carusela, M. F. |9 72482 | |
| 700 | 1 | |a Izquierdo, E. D. |9 72483 | |
| 773 | |t Physica A: Statistical Mechanics and its Applications |g vol.392, no.20 (2013), p.4856-4867 | ||
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| 900 | |a ^tComplementarity relation for irreversible processes near steady states | ||
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| 900 | |a ^aSantini^bE.S.^tComissão Nacional de Energia Nuclear, Rua General Severiano 90, Botafogo [22290-901], Rio de Janeiro, RJ, Brazil | ||
| 900 | |a ^aSantini, E.S.^tUniversidad Nacional de General Sarmiento, Instituto de Ciencias, J^tM^tGutiérrez 1150, Malvinas Argentinas (1613), Pcia de Buenos Aires, Argentina | ||
| 900 | |a ^aSantini, E.S.^tCentro Brasileiro de Pesquisas Físicas - ICRA-BR, Rua Dr. Xavier Sigaud 150, Urca (22290-180), Rio de Janeiro, RJ, Brazil | ||
| 900 | |a ^aCarusela^bM.F.^tUniversidad Nacional de General Sarmiento, Instituto de Ciencias, J. M. Gutiérrez 1150, Malvinas Argentinas [1613], Pcia de Buenos Aires, Argentina | ||
| 900 | |a ^aCarusela, M.F.^tConsejo Nacional de Investigaciones Científicas y Técnicas, Av. Rivadavia 1917, (1033)-Buenos Aires, Argentina | ||
| 900 | |a ^aIzquierdo, E.D.^tCiclo Básico Común, Universidad de Buenos Aires, Cdad. Universitaria, Pab. 3, (1428) Buenos Aires, Argentina | ||
| 900 | |a ^aIzquierdo, E.D.^tFacultad de Agronomía, Universidad de Buenos Aires, Av. San Martín 4453, Cap^tFed., Buenos Aires (C1417DSE), Argentina | ||
| 900 | |a ^tPhysica A: Statistical Mechanics and its Applications^cPhys A Stat Mech Appl | ||
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| 900 | |a Vol. 392, no. 20 | ||
| 900 | |a 4867 | ||
| 900 | |a FLUCTUATION PHENOMENA | ||
| 900 | |a LANGEVIN EQUATION | ||
| 900 | |a STOCHASTIC ENERGETICS | ||
| 900 | |a THERMODYNAMICS | ||
| 900 | |a COMPLEMENTARITY RELATIONS | ||
| 900 | |a IRREVERSIBLE PROCESS | ||
| 900 | |a PRECISE DETERMINATIONS | ||
| 900 | |a QUASI-EQUILIBRIUM PROCESS | ||
| 900 | |a UNCERTAINTY PRINCIPLES | ||
| 900 | |a DIFFERENTIAL EQUATIONS | ||
| 900 | |a FREE ENERGY | ||
| 900 | |a RNA | ||
| 900 | |a STOCHASTIC SYSTEMS | ||
| 900 | |a STATISTICAL MECHANICS | ||
| 900 | |a A relation giving a minimum for the irreversible work in quasi-equilibrium processes was derived by Sekimoto et al. [K. Sekimoto, S. Sasa, J. Phys. Soc. Japan 66 [1997] 3326] in the framework of stochastic energetics. This relation can also be written as a type of "uncertainty principle" in such a way that the precise determination of the Helmholtz free energy through the observation of the work [W] requires an indefinitely large experimental time delta t. In the present article, we extend this relation to the case of quasi-steady processes by using the concept of non-equilibrium Helmholtz free energy. We give a formulation of the second law for these processes that extends that presented by Sekimoto [K. Sekimoto, Prog. Theoret. Phys. Suppl. No. 130 [1998] 17] by a term of the first order in the inverse of the experimental time. As an application of our results, two possible experimental situations are considered: stretching of a RNA molecule and the drag of a dipolar particle in the presence of a gradient of electric force. | ||
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