Carboxylated zinc phthalocyanines III. Quenching of excited singlet and triplet states by quinones in CTAC micelles

Deactivation of zinc dicarboxydiamide phthalocyanine (ZnPc) by quinones was investigated in hexadecyltrimethylammonium chloride micelles by fluorescence and triplet quenching experiments. Fluorescence data were handled according to the method of Encinas and Lissi (Chem. Phys. Lett., 91 (1982) 55) to...

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Autor principal: Daraio, Marta Edit
Otros Autores: Aramendia, P.F, San Román, E.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1994
Acceso en línea:Registro en Scopus
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100 1 |a Daraio, Marta Edit 
245 1 0 |a Carboxylated zinc phthalocyanines III. Quenching of excited singlet and triplet states by quinones in CTAC micelles 
260 |c 1994 
270 1 0 |m Aramendia, P.F.; INQUIMAE, Departamento de Química Inorgánica, Analitica y Química Física, Facultad de Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
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506 |2 openaire  |e Política editorial 
520 3 |a Deactivation of zinc dicarboxydiamide phthalocyanine (ZnPc) by quinones was investigated in hexadecyltrimethylammonium chloride micelles by fluorescence and triplet quenching experiments. Fluorescence data were handled according to the method of Encinas and Lissi (Chem. Phys. Lett., 91 (1982) 55) to derive quencher partition constants. The same data were used to obtain singlet quenching constants. Triplet quenching and quencher exit rate constants were obtained by steady state singlet oxygen phosphorescence detection. The correlation of the quenching rate constants with the redox potentials indicates electron transfer quenching. © 1994.  |l eng 
536 |a Detalles de la financiación: (CONICET). This work was supportedb y grants from Stiftung Volkswagenwerk( Germany) and Fundacidn Antorchas (Argentina).W e acknowledge Professor S.E. Braslavslq (MPI-Strahlen-chemie,M iilhkim, Germany)f or help and advice. We are indebtedt o Dr. Elsa Abuin (Universidad de Santiagod e Chile, Chile) for valuabled iscus-sions,D r. E. Quel and Dr. A. Peuriot (CZTEFA, BuenosA ires) for the use of facilitiest o measure the time-resolvedn ear-IR emissiona nd Professor K. Schaffner( MPI-Strahlenchemie)f or constant support. 
593 |a INQUIMAE, Departamento de Química Inorgánica, Analitica y Química Física, Facultad de Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
700 1 |a Aramendia, P.F. 
700 1 |a San Román, E. 
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