Complex anthocyanins from Ipomoea congesta

Six acylated anthocyanins have been isolated from the flowers of Ipomoea congesta R. Brown. One has been previously described as an acylated peonidin derivative. Three others are isomers, derived from peonidin-3-(caffeylsophoroside)-5-glucoside. The fifth was characterised as peonidin-3-(p-coumarylc...

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Autor principal: Pomilio, A.B
Otros Autores: Sproviero, J.F
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1972
Acceso en línea:Registro en Scopus
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245 1 0 |a Complex anthocyanins from Ipomoea congesta 
260 |c 1972 
270 1 0 |m Pomilio, A.B. 
506 |2 openaire  |e Política editorial 
504 |a Pomilio, Sproviero, (1972) Phytochem., 11, p. 1125 
504 |a Imbert, Seaforth, Williams, (1966) J. Am. Soc. Hort. Sci., 88, p. 481 
504 |a Birkofer, Kaiser, Koch, Donike, Wolf, (1963) Z. Naturforsch., 18 b, p. 631 
504 |a Harborne, (1967) Comparative Biochemistry of the Flavonoids, , Academic Press, London 
504 |a Albach, Kepner, Webb, Structures of Acylated Anthocyan Pigments in Vitis vinifera Variety Tinta Pinheira. Identification of Anthocyanidin, Sugar, and Acid Moieties (1965) Journal of Food Science, 30, p. 69 
504 |a Chandler, Harper, Identification of saccharides in anthocyanins and other flavonoids (1961) Australian Journal of Chemistry, 14, p. 586 
504 |a Harborne, (1965) Phytochem., 4, p. 107 
504 |a Harborne, (1960) Biochem. J., 74, p. 262 
504 |a Harborne, (1958) Biochem. J., 70, p. 22 
504 |a Chen, Luh, Anthocyanins in Royalty Grapes (1967) Journal of Food Science, 32, p. 66 
504 |a Swain, (1953) Biochem. J., 53, p. 200 
504 |a Geissman, Jorgenson, Harborne, (1953) Chem. & Ind., p. 1389 
504 |a Tanchev, Timberlake, (1969) Phytochem., 8, p. 1825 
504 |a Nakanishi, (1962) Infrared Absorption Spectroscopy, p. 61. , Practical, Holden-Day, San Francisco 
504 |a Birkofer, Kaiser, Kosmol, Romussi, Donike, Michaelis, (1966) Ann., 699, p. 223 
504 |a Geissman, Harborne, (1955) Arch. Biochem. Biophys., 55, p. 447 
520 3 |a Six acylated anthocyanins have been isolated from the flowers of Ipomoea congesta R. Brown. One has been previously described as an acylated peonidin derivative. Three others are isomers, derived from peonidin-3-(caffeylsophoroside)-5-glucoside. The fifth was characterised as peonidin-3-(p-coumarylcaffeylsophoroside)-5-glucoside and the last as peonidin-3-(coumarylsophoroside)-5-glucoside. It is noteworthy that the anthocyanins found in this species have the same glycosidic pattern, 3-sophoroside-5-glucoside, as those reported for the cyanidin derivatives in Ipomoea cairica flowers. Acylated anthocyanin occurrence in Tubiflorae order is of chemotaxonomical value. © 1972.  |l eng 
536 |a Detalles de la financiación: EXPERIMENTAL Flowers were collectedf rom plants growing in Buenos Aires and La Plata from November to April. Extraction was carried out with 0.1% HCI-MeOH, at 0”, in the darknessu nder N2. Oxidation, acid and alkaline hydrolysesw erecarried out accordingt o the conventionalm ethodse arlierr eported.’ Acknowledgements-Waer e gratefult o Dr. Crisci for supplyingu s with somes ampleso f I. congestaP. art of this work was supportedb y a grantf rom the Instituto National de Farmacologiay Bromatologia.O ne of us (ABP) thanks the Consejo National de InvestigacionesC ientiticasy Tecnicasf or a researchf ellowship. 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, Argentina 
690 1 0 |a CONVOLVULACEAE 
690 1 0 |a IPOMOEA CONGESTA 
690 1 0 |a PEONIDIN-3-SOPHOROSIDE-5-GLUCOSIDE CINNAMIC ESTERS 
700 1 |a Sproviero, J.F. 
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