Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent
Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that...
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| Otros Autores: | , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
Elsevier Ltd
2016
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 15310caa a22015497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-16136 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250423093025.0 | ||
| 008 | 190411s2016 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84949678335 | |
| 024 | 7 | |2 cas |a citric acid, 126-44-3, 5949-29-1, 77-92-9, 8002-14-0; dimethyl sulfoxide, 67-68-5; glycerol, 56-81-5; starch, 9005-25-8, 9005-84-9; water, 7732-18-5; Citric Acid; Cross-Linking Reagents; Dimethyl Sulfoxide; Glycerol; Starch; Water | |
| 030 | |a CAPOD | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Seligra, P.G. | |
| 245 | 1 | 0 | |a Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
| 260 | |b Elsevier Ltd |c 2016 | ||
| 270 | 1 | 0 | |m Famá, L.; LP and MC, Dep. de Física - IFIBA, CONICET, FCEyN, UBA, Ciudad UniversitariaArgentina |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that avoided starch retrogradation and maintained the degradability in compost, occurring only six days after the films without citric acid. A simulation of the gelatinization process of starch-glycerol with and without CA, using a differential thermal analysis device, showed that the system with CA completed the gelatinization 5 °C before than the other and, CA first reacted with glycerol and then starch-glycerol-CA reaction occurred. The temperature at which the gelatinization process was carried out was critical to obtain the best results. An increase of gelatinization process temperature at 85 °C in system with CA, led to a worsening on WVP and its integrity after a swelling process with dimethylsulphoxide (DMSO), compared to the films processed at 75 °C. © 2015 Elsevier Ltd. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, CAPES 2014-2015 BR/13/13, UBACYT, 2014-2017 No., 20020130100495BA | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, —2012-1093 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP 2014-2016 No. 11220120100508CO | ||
| 536 | |a Detalles de la financiación: The authors wish to acknowledge the support and collaboration of the following organizations: ANPCyT—2012-1093, CONICET PIP 2014-2016 No. 11220120100508CO, Universidad de Buenos Aires UBACYT 2014-2017 No. 20020130100495BA, CAPES 2014-2015 BR/13/13. | ||
| 593 | |a LP and MC, Dep. de Física - IFIBA, CONICET, FCEyN, UBA, Ciudad Universitaria, CABA, 1428, Argentina | ||
| 593 | |a Instituto de Tecnología en Polímeros y Nanotecnología ITPN (UBA-CONICET), FCEyN, UBA, Av. Las Heras 2214, CABA, C1127AAQ, Argentina | ||
| 690 | 1 | 0 | |a BIODEGRADABILITY |
| 690 | 1 | 0 | |a BIODEGRADABLE EDIBLE FILMS |
| 690 | 1 | 0 | |a CITRIC ACID |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a STARCH |
| 690 | 1 | 0 | |a AMORPHOUS FILMS |
| 690 | 1 | 0 | |a BIODEGRADABILITY |
| 690 | 1 | 0 | |a BIODEGRADATION |
| 690 | 1 | 0 | |a CITRIC ACID |
| 690 | 1 | 0 | |a COMPOSTING |
| 690 | 1 | 0 | |a DIFFERENTIAL THERMAL ANALYSIS |
| 690 | 1 | 0 | |a GELATION |
| 690 | 1 | 0 | |a GLYCEROL |
| 690 | 1 | 0 | |a STARCH |
| 690 | 1 | 0 | |a THERMOANALYSIS |
| 690 | 1 | 0 | |a CROSS LINKING AGENTS |
| 690 | 1 | 0 | |a DEGRADABILITY |
| 690 | 1 | 0 | |a EDIBLE FILMS |
| 690 | 1 | 0 | |a PROCESS TEMPERATURE |
| 690 | 1 | 0 | |a STARCH RETROGRADATION |
| 690 | 1 | 0 | |a SWELLING PROCESS |
| 690 | 1 | 0 | |a WATER VAPOR PERMEABILITY |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a CITRIC ACID |
| 690 | 1 | 0 | |a CROSS LINKING REAGENT |
| 690 | 1 | 0 | |a DIMETHYL SULFOXIDE |
| 690 | 1 | 0 | |a GLYCEROL |
| 690 | 1 | 0 | |a STARCH |
| 690 | 1 | 0 | |a WATER |
| 690 | 1 | 0 | |a BIOREMEDIATION |
| 690 | 1 | 0 | |a CHEMISTRY |
| 690 | 1 | 0 | |a INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a MICROBIOLOGY |
| 690 | 1 | 0 | |a PERMEABILITY |
| 690 | 1 | 0 | |a TEMPERATURE |
| 690 | 1 | 0 | |a THERMOGRAVIMETRY |
| 690 | 1 | 0 | |a BIODEGRADATION, ENVIRONMENTAL |
| 690 | 1 | 0 | |a CITRIC ACID |
| 690 | 1 | 0 | |a CROSS-LINKING REAGENTS |
| 690 | 1 | 0 | |a DIMETHYL SULFOXIDE |
| 690 | 1 | 0 | |a GLYCEROL |
| 690 | 1 | 0 | |a PERMEABILITY |
| 690 | 1 | 0 | |a SOIL MICROBIOLOGY |
| 690 | 1 | 0 | |a SPECTROSCOPY, FOURIER TRANSFORM INFRARED |
| 690 | 1 | 0 | |a STARCH |
| 690 | 1 | 0 | |a TEMPERATURE |
| 690 | 1 | 0 | |a THERMOGRAVIMETRY |
| 690 | 1 | 0 | |a WATER |
| 700 | 1 | |a Medina Jaramillo, C. | |
| 700 | 1 | |a Famá, L. | |
| 700 | 1 | |a Goyanes, Silvia Nair | |
| 773 | 0 | |d Elsevier Ltd, 2016 |g v. 138 |h pp. 66-74 |p Carbohydr Polym |x 01448617 |w (AR-BaUEN)CENRE-603 |t Carbohydrate Polymers | |
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