New dimeric surfactants from alkyl glucosides

Carbohydrate containing dimeric (or gemini) surfactants were synthesized starting from D-glucose. Three different spacers (glutaryl, succinyl and terephthaloyl) were used to link the sugar moieties through O-2 or O-6. The critical micellar concentration (CMC) for these new compounds was ten-fold sma...

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Autor principal: Castro, M.J.L
Otros Autores: Kovensky, J., Fernández Cirelli, A.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1999
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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030 |a TETRA 
100 1 |a Castro, M.J.L. 
245 1 0 |a New dimeric surfactants from alkyl glucosides 
260 |c 1999 
270 1 0 |m Cirelli, A.F.; CIHIDECAR, CONICET, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina; email: afc@rec.uba.ar 
506 |2 openaire  |e Política editorial 
504 |a Zana, R., Benrraou, M., Rueff, R., (1991) Langmuir, 7, pp. 1072-1075 
504 |a Menger, F.M., Littau, C.A., (1991) J. Am. Chem. Soc., 113, pp. 1451-1452 
504 |a Menger, F.M., Littau, C.A., (1993) J. Am. Chem. Soc., 115, pp. 10083-10090 
504 |a Karaborni, S., Esselink, K., Hilbers, P.A.J., Smit, B., Karthauser, J., Van Os, N.M., Zana, R., (1994) Science, 266, pp. 254-256 
504 |a Hue, Q., Leon, R., Petroff, P.M., Stucky, G.D., (1995) Science, 268, pp. 1324-1327 
504 |a Perez, L., Torres, J.L., Manresa, A., Solans, C., Infante, M.R., (1996) Langmuir, 12, pp. 5296-5301 
504 |a Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., (1997) Tetrahedron Lett., 38, pp. 3995-3998 
504 |a Morcuende, A., Valverde, S., Herradón, B., (1994) Synlett., pp. 89-95 
504 |a Herradón, B., Morcuende, A., Valverde, S., (1995) Synlett., pp. 455-458 
504 |a David, S., Hanessian, S., (1985) Tetrahedron, 41, pp. 643-663 
504 |a Dewar, M.J.S., Zoebisch, E.F., Healy, E.F., Stewart, J.J.P., (1985) J. Am. Chem. Soc., 107, pp. 3902-3909. , Hyperchem 5.0, AMP AC version 5.0, Semichem Inc., 7128 Summit. The parameters of the AMI method belong to 
504 |a Holmberg, K., (1998) Novel Surfactants. Preparation, Applications, and Biodegradability, 74, pp. 255-256. , Surfactant Science Series, Marcel Dekker Inc 
504 |a Zana, R., Talmon, Y., (1993) Nature, 362, pp. 228-230 
504 |a Danino, D., Talmon, Y., Zana, R., (1995) Langmuir, 11, pp. 1448-1456 
504 |a Ferro, V., Mocerino, M., Stick, R.V., Tilbrook, D.M.G., (1988) Aust. J. Chem., 41, pp. 813-815 
504 |a Becher, P., (1965) Emulsions, Theory and Practice, pp. 355-356. , Litton Educational Publishing 
504 |a Lide, D.R., (1997) CRC Handbook of Chemistry and Physics, pp. 6-135. , CRC Press: Boca Raton, FL 
520 3 |a Carbohydrate containing dimeric (or gemini) surfactants were synthesized starting from D-glucose. Three different spacers (glutaryl, succinyl and terephthaloyl) were used to link the sugar moieties through O-2 or O-6. The critical micellar concentration (CMC) for these new compounds was ten-fold smaller than that of their monomeric counterpart.  |l eng 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, T6cnicas 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: This work was carried out with the financial contribution of UBA (Universidad de Buenos Aires) and CONICET (Consejo Nacional de Investigaciones Cientificas y T6cnicas). Elemental analyses were performed by UMYMFOR (CONICET). M. Castro thanks UBA for a fellowship. J. Kovensky and A. Fem~dez Cirelli are Research Members of CONICET. 
593 |a Ctro. Invest. en Hidratos de Carbono, Departamento de Quimica Organica, Universidad de Buenos Aires, Pabellón II, 3er. Piso, 1428 Buenos Aires, Argentina 
690 1 0 |a DIMERS 
690 1 0 |a ESTERS 
690 1 0 |a GLYCOSIDES 
690 1 0 |a SURFACTANTS 
690 1 0 |a ALKYL ARYL ETHER 
690 1 0 |a GLUCOSE 
690 1 0 |a GLUCOSIDE 
690 1 0 |a SURFACTANT 
690 1 0 |a ARTICLE 
690 1 0 |a CONCENTRATION (PARAMETERS) 
690 1 0 |a DIMERIZATION 
690 1 0 |a ESTERIFICATION 
690 1 0 |a HYDROGENATION 
690 1 0 |a MICELLE 
690 1 0 |a NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a REACTION ANALYSIS 
690 1 0 |a STRUCTURE ANALYSIS 
690 1 0 |a SURFACE TENSION 
690 1 0 |a SYNTHESIS 
700 1 |a Kovensky, J. 
700 1 |a Fernández Cirelli, A. 
773 0 |d 1999  |g v. 55  |h pp. 12711-12722  |k n. 44  |p Tetrahedron  |x 00404020  |w (AR-BaUEN)CENRE-45  |t Tetrahedron 
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