Gemini surfactants from alkyl glucosides
1,5-Bis-[6-O-(n-butyl α-D-glucopyranosid)] glutarate 7 was synthesized starting from D-glucose by a simple procedure. The anomeric mixture of alkylglucosides was separated by flash chromatography of their peracetates. Detritylation in neutral conditions is described. This is the first example of a n...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
Elsevier Ltd
1997
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 04139caa a22005657a 4500 | ||
|---|---|---|---|
| 001 | PAPER-20060 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205127.0 | ||
| 008 | 190411s1997 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0031007068 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a TELEA | ||
| 100 | 1 | |a Castro, M.J.L. | |
| 245 | 1 | 0 | |a Gemini surfactants from alkyl glucosides |
| 260 | |b Elsevier Ltd |c 1997 | ||
| 270 | 1 | 0 | |m Cirelli, A.F.; Departamento Quimica Organica, Fac. Ciencias Exactas y Naturales, Universidad Buenos Aires, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Menger, F.M., Littau, C.A., (1991) J. Am. Chem. Soc., 113, pp. 1451-1452 | ||
| 504 | |a Karaborni, S., Esselink, K., Hilbers, P.A.J., Smit, B., Karthäuser, J., Van Os, N.M., Zana, R., (1994) Science, 265, pp. 254-256 | ||
| 504 | |a Huo, Q., Leon, R., Petroff, P.M., Stucky, G.D., (1995) Science, 268, pp. 1324-1327 | ||
| 504 | |a Gouéth, P., Ramiz, A., Ronco, G., Mackenzie, G., Villa, P., (1995) Carbohydr. Res., 266, pp. 171-189 | ||
| 504 | |a Schmidt, R.R., Jankowski, K., (1996) Liebigs Ann., pp. 867-879 | ||
| 504 | |a Matsumura, S., Imai, K., Yoshikawa, S., Kawada, K., Uchibori, T., (1990) J. Am. Oil. Chem. Soc., 67, pp. 996-1001 | ||
| 504 | |a AMPAC Version 5.0, , Semichem Inc., 7128 Summit | ||
| 504 | |a Dewar, M.J.S., Zoebisch, E.F., Healy, E.F., Stewart, J.J.P., (1985) J. Am. Chem. Soc., 107, pp. 3902-3909 | ||
| 504 | |a Lorenz, K., Balzer, W., Wolf, H., Trieselt, W., Busse, G., DE 3,232,791; (1984) C. A., 101, p. 73052 | ||
| 504 | |a Pyridinium chloride (0.75 eq.) in refluxing ethanol was found to be a mild method of detritylation, yielding quantitatively the deprotected product. These neutral conditions may be useful for detritylation of carbohydrate derivatives having acid-sensitive protecting groups and have been successfully tested in our lab on mono- and ditrityl derivatives; Grindley, T.B., Namazi, H., (1996) Tetrahedron Lett., 37, pp. 991-994 | ||
| 504 | |a note; note | ||
| 520 | 3 | |a 1,5-Bis-[6-O-(n-butyl α-D-glucopyranosid)] glutarate 7 was synthesized starting from D-glucose by a simple procedure. The anomeric mixture of alkylglucosides was separated by flash chromatography of their peracetates. Detritylation in neutral conditions is described. This is the first example of a non ionic gemini surfactant where alkyl glucosides are linked through a spacer at C-6. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: ACKNOWLEDGEMENTS: This work was carried out with the financial contribution of UBA (Universidad de Buenos Aires) and CONICET (Consejo National de Investigaciones Cientificas y Tecnicas). M. Castro thanks Universidad de Buenos Aires for a fellowship. Elemental analyses were performed by UMYMFOR (CONICET). | ||
| 593 | |a Ctro. Invest. en Hidratos de Carbono, Depto. de Quim. Orgánica, Ciudad Universitaria, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a GLUTARIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a GLYCOSIDE |
| 690 | 1 | 0 | |a SURFACTANT |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CHEMICAL REACTION |
| 690 | 1 | 0 | |a DRUG SYNTHESIS |
| 690 | 1 | 0 | |a MOLECULAR DYNAMICS |
| 700 | 1 | |a Kovensky, J. | |
| 700 | 1 | |a Fernández Cirelli, A. | |
| 773 | 0 | |d Elsevier Ltd, 1997 |g v. 38 |h pp. 3995-3998 |k n. 23 |p TETRAHEDRON LETT. |x 00404039 |w (AR-BaUEN)CENRE-415 |t Tetrahedron Letters | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0031007068&doi=10.1016%2fS0040-4039%2897%2900817-4&partnerID=40&md5=23ec210e5208134982adc65f33c4e9b8 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/S0040-4039(97)00817-4 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00404039_v38_n23_p3995_Castro |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v38_n23_p3995_Castro |y Registro en la Biblioteca Digital |
| 961 | |a paper_00404039_v38_n23_p3995_Castro |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 81013 | ||