Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry an...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
Elsevier Ltd
2004
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 09075caa a22012737a 4500 | ||
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| 001 | PAPER-21193 | ||
| 003 | AR-BaUEN | ||
| 005 | 20251105104853.0 | ||
| 008 | 190411s2004 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-3342881089 | |
| 024 | 7 | |2 cas |a 1,3 butadiene, 106-99-0, 25339-57-5; rubber, 9006-04-6; sulfur, 13981-57-2, 7704-34-9 | |
| 030 | |a POLMA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Salgueiro, Walter Alberto | |
| 245 | 1 | 0 | |a Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
| 260 | |b Elsevier Ltd |c 2004 | ||
| 270 | 1 | 0 | |m Somoza, A.; IFIMAT-UNCentro, Pinto 399, B7000GHG, Tandil, Argentina; email: asomoza@exa.unicen.edu.ar |
| 504 | |a Payne, A.R., (1965) Reinforcement of Elastomers, p. 64. , G. Kraus. New York: Interscience | ||
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd. |l eng | |
| 536 | |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, UBACYT X-150 | ||
| 536 | |a Detalles de la financiación: Ministero dell’Istruzione, dell’Università e della Ricerca, MIUR | ||
| 536 | |a Detalles de la financiación: Fundación Antorchas | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP N o 02825/01 | ||
| 536 | |a Detalles de la financiación: Universidad Nacional del Centro de la Provincia de Buenos Aires | ||
| 536 | |a Detalles de la financiación: This work was supported by Consejo Nacional de Investigaciones Cientı́ficas y Técnicas (PIP N o 02825/01), Comisión de Investigaciones Cientı́ficas de la Provincia de Buenos Aires, Secretarı́a de Ciencia y Técnica (UNCentro), University of Buenos Aires (Project UBACYT X-150) and Fundación Antorchas, Argentina. G.C. acknowledges the support by the Ministero dell'Istruzione, dell'Università e della Ricerca through the MIUR-Cofin 2002 project (prot. n. 2002033184_005). O. Toscano and M.T. Maldonado are acknowledged by their technical assistance. | ||
| 593 | |a IFIMAT-UNCentro, Pinto 399, B7000GHG, Tandil, Argentina | ||
| 593 | |a Comn. Invest. Cie. Provincia B., Calle 526 e Loy 11, 1900 la Plata, B7000GHG, Tandil, Argentina | ||
| 593 | |a LPMPyMC, Departamento de Física, Fac. Cie. Exact. Y Nat., Univ. N., Buenos Aires, Argentina | ||
| 593 | |a Consejo Nac. Invest. Cie. Y T., Argentina | ||
| 593 | |a Ist. Naz. Fis. Della Materia D., Politecnico di Milano, Piazza Leonardo Da Vinci 32, I-20133, Milano, Italy | ||
| 593 | |a Inst. de Fisica de Materiales Tandil, Fisica, Pinto 399, 7000 Tandil, Argentina., Argentina | ||
| 690 | 1 | 0 | |a FREE VOLUME |
| 690 | 1 | 0 | |a NANOHOLE |
| 690 | 1 | 0 | |a SBR COPOLYMER |
| 690 | 1 | 0 | |a COPOLYMERS |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a DIFFERENTIAL SCANNING CALORIMETRY |
| 690 | 1 | 0 | |a GLASS TRANSITION |
| 690 | 1 | 0 | |a POLYSULFIDES |
| 690 | 1 | 0 | |a POSITRON ANNIHILATION SPECTROSCOPY |
| 690 | 1 | 0 | |a DYNAMICAL MECHANICAL ANALYSIS |
| 690 | 1 | 0 | |a NANOHOLES |
| 690 | 1 | 0 | |a POSITRON ANNIHILATION LIFETIME SPECTROSCOPY |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a 1,3 BUTADIENE |
| 690 | 1 | 0 | |a COPOLYMER |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a STYRENE DERIVATIVE |
| 690 | 1 | 0 | |a SULFUR |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CHEMICAL ANALYSIS |
| 690 | 1 | 0 | |a CHEMICAL STRUCTURE |
| 690 | 1 | 0 | |a CROSS LINKING |
| 690 | 1 | 0 | |a DENSITY |
| 690 | 1 | 0 | |a DIFFERENTIAL SCANNING CALORIMETRY |
| 690 | 1 | 0 | |a DYNAMICS |
| 690 | 1 | 0 | |a GLASS TRANSITION TEMPERATURE |
| 690 | 1 | 0 | |a POSITRON |
| 690 | 1 | 0 | |a SPECTROSCOPY |
| 690 | 1 | 0 | |a POLYMER SCIENCE |
| 700 | 1 | |a Marzocca, Angel José | |
| 700 | 1 | |a Somoza, Alberto Horacio | |
| 700 | 1 | |a Consolati, Gianni | |
| 700 | 1 | |a Cerveny, S. | |
| 700 | 1 | |a Quasso, F. | |
| 700 | 1 | |a Goyanes, Silvia Nair | |
| 773 | 0 | |d Elsevier Ltd, 2004 |g v. 45 |h pp. 6037-6044 |k n. 17 |p Polymer |x 00323861 |w (AR-BaUEN)CENRE-350 |t Polymer | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-3342881089&doi=10.1016%2fj.polymer.2004.05.008&partnerID=40&md5=07ef78651b1a4beb2c2c2f10162b2ea1 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.polymer.2004.05.008 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00323861_v45_n17_p6037_Salgueiro |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00323861_v45_n17_p6037_Salgueiro |y Registro en la Biblioteca Digital |
| 961 | |a paper_00323861_v45_n17_p6037_Salgueiro |b paper |c PE | ||
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| 999 | |c 82146 | ||