A SAXS and swelling study of cured natural rubber/styrene-butadiene rubber blends
A small-angle X-ray scattering (SAXS) and swelling study of natural rubber and styrene-butadiene rubber blends (NR/SBR) is presented. To this aim, specimens of NR and SBR and blends with 75/25, 50/50, and 25/75 NR/SBR ratios (in phr) were prepared at a cure temperature of 433 K and the optimum cure...
Guardado en:
| Autor principal: | |
|---|---|
| Otros Autores: | , , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2009
|
| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 07162caa a22011417a 4500 | ||
|---|---|---|---|
| 001 | PAPER-23020 | ||
| 003 | AR-BaUEN | ||
| 005 | 20251105104626.0 | ||
| 008 | 190411s2009 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-72449131831 | |
| 030 | |a JPBPE | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Salgueiro, Walter Alberto | |
| 245 | 1 | 2 | |a A SAXS and swelling study of cured natural rubber/styrene-butadiene rubber blends |
| 260 | |c 2009 | ||
| 270 | 1 | 0 | |m Somoza, A.; IFIMAT-UNCentro, Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil, Argentina; email: asomoza@exa.unicen.edu.ar |
| 504 | |a Hess, W.M., Herd, C.R., Vegvari, P.C., (1993) Rubber Chem Technol, 66, pp. 329-375 | ||
| 504 | |a Sircar, A.K., (1981) Thermal Characterization of Polymeric Materials, pp. 887-1378. , Turi, E. A., Ed.; Academic Press: San Diego | ||
| 504 | |a Morfin, I., Ehrburger-Dolle, F., Grillo, I., Livet, F., Bley, F.J., (2006) Synchrotron Rad, 13, pp. 445-452 | ||
| 504 | |a Ehrburger-Dolle, F., Bley, F., Geissler, E., Livet, F., Morfin, I., Rochas, C., (2003) Macromol Symp, 200, pp. 157-168 | ||
| 504 | |a Horston, D.J., Song, M., (2000) J Appl Polym Sci, 76, pp. 1791-1798 | ||
| 504 | |a Mallon, P.E., McGill, W.J., (1999) J Appl Polym Sci, 74, pp. 1264-1270 | ||
| 504 | |a Goyanes, S., Lopez, C.C., Rubiolo, G.H., Quaso, F., Marzocca, A.J., (2008) Eur Polym J, 44, pp. 1525-1534 | ||
| 504 | |a Marzocca, A.J., Cerveny, S., Salgueiro, W., Somoza, A., Gonzalez, L., (2002) Phys Rev E, 65, pp. 0218011-0218015 | ||
| 504 | |a Salgueiro, W., Marzocca, A.J., Somoza, A., Consolati, G., Cerveny, S., Quasso, F., Goyanes, S., (2004) Polymer, 45, pp. 6037-6044 | ||
| 504 | |a Salgueiro, W., Somoza, A., Torriani, I.L., Marzocca, A.J., (2007) J Polym Sci Part B: Polym Phys, 45, pp. 2966-2971 | ||
| 504 | |a Cunneen, J.I., Russell, R.M., (1970) Rubber Chem Technol, 43, pp. 1215-1224 | ||
| 504 | |a Flory, P.J., Rehner, J., (1943) J Chem Phys, 11, pp. 512-520 | ||
| 504 | |a Flory, P.J., Rehner, J., (1943) J Chem Phys, 11, pp. 521-526 | ||
| 504 | |a Kraus, K., (1957) Rubber Chem Technol, 30, pp. 928-951 | ||
| 504 | |a Marzocca, A.J., (2007) Eur Polym J, 43, pp. 2682-2689 | ||
| 504 | |a (1997) CRC Handbook of Chemistry and Physics, pp. 3-55. , Lide, D. R., Ed.; CRC Press: New York | ||
| 504 | |a Queslel, J.P., Mark, J.E., (1985) J Chem Phys, 82, pp. 3449-3452 | ||
| 504 | |a Balta-Calleja, F.J., Vonk, C.G., (1989) Polymer Science Library 8, , Elsevier: Amsterdam | ||
| 504 | |a Akiba, M., Hashim, A.S., (1997) Prog Polym Sci, 22, pp. 475-521 | ||
| 504 | |a Cerveny, S., Marzocca, A.J., (1999) J Appl Polym Sci, 74, pp. 2747-2755 | ||
| 504 | |a Chough, S.H., Chang, D.H., (1996) J Appl Polym Sci, 61, pp. 449-454 | ||
| 504 | |a Klei, B., Koenig, J.L., (1997) Rubber Chem Technol, 70, pp. 231-242 | ||
| 504 | |a Pelliccioli, L., Mowdood, S.K., Negroni, F., Parker, D.D., Koenig, J.L., (2002) Rubber Chem Technol, 75, pp. 1-12 | ||
| 504 | |a Loo, C.T., (1974) Polymer, 15, pp. 357-365 | ||
| 504 | |a Mukhopadhyay, R., De, S.K., (1978) Rubber Chem Technol, 51, pp. 704-716 | ||
| 504 | |a Mori, M., Koening, J.L., (1995) Rubber Chem Technol, 68, pp. 551-562 | ||
| 504 | |a Marzocca, A.J., Steren, C., Raimondo, R., Cerveny, S., (2004) Polym Int, 53, pp. 646-655 | ||
| 504 | |a Gardiner, J.D., (1968) Rubber Chem Technol, 41, pp. 1312-1328 | ||
| 504 | |a Rehner, J., Wei, P.E., (1969) Rubber Chem Technol, 42, pp. 985-999 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a A small-angle X-ray scattering (SAXS) and swelling study of natural rubber and styrene-butadiene rubber blends (NR/SBR) is presented. To this aim, specimens of NR and SBR and blends with 75/25, 50/50, and 25/75 NR/SBR ratios (in phr) were prepared at a cure temperature of 433 K and the optimum cure time (t100). This time was obtained from rheometer torque curves. The system of cure used in the samples was sulfur/n-t-butyl-2-benzothiazole sulfenamide. From swelling tests of the cured samples, information about the molecular weight of the network chain between chemical crosslinks was obtained. For all cured compounds, in the Lorentz plots built from SAXS scattering curves, a maximum of the scattering vector q around 0.14 Å -1 was observed. However, the q position shows a linear-like shift toward lower values when the SBR content in the SBR/NR blend increases. In pure NR or SBR the q values show a different tendency. The results obtained are discussed in terms of the existence of different levels of vulcanization for each single phase forming the blend and the existence of a third level of vulcanization located in the interfacial NR/SBR layer. © 2009 Wiley Periodicals, Inc. |l eng | |
| 593 | |a IFIMAT-UNCentro, Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil, Argentina | ||
| 593 | |a LPMPyMC, Departamento de Física, Ciudad Universitaria, Pabellón I, C1428EGA Buenos Aires, Argentina | ||
| 593 | |a Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas, CP 6165, 13084-971 Campinas, Sao Paulo, Brazil | ||
| 690 | 1 | 0 | |a BLENDS |
| 690 | 1 | 0 | |a NR |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a RUBBER BLENDS |
| 690 | 1 | 0 | |a SAXS |
| 690 | 1 | 0 | |a SBR |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a BENZOTHIAZOLES |
| 690 | 1 | 0 | |a BUTADIENE RUBBER |
| 690 | 1 | 0 | |a CHEMICAL CROSSLINKS |
| 690 | 1 | 0 | |a CURE TEMPERATURE |
| 690 | 1 | 0 | |a CURE TIME |
| 690 | 1 | 0 | |a LORENTZ |
| 690 | 1 | 0 | |a NATURAL RUBBER |
| 690 | 1 | 0 | |a NETWORK CHAINS |
| 690 | 1 | 0 | |a NR |
| 690 | 1 | 0 | |a Q-VALUES |
| 690 | 1 | 0 | |a RUBBER BLENDS |
| 690 | 1 | 0 | |a SCATTERING CURVE |
| 690 | 1 | 0 | |a SCATTERING VECTORS |
| 690 | 1 | 0 | |a SINGLE PHASE |
| 690 | 1 | 0 | |a SMALL ANGLE X-RAY SCATTERING |
| 690 | 1 | 0 | |a STYRENE BUTADIENE RUBBER |
| 690 | 1 | 0 | |a SULFENAMIDES |
| 690 | 1 | 0 | |a SWELLING STUDIES |
| 690 | 1 | 0 | |a SWELLING TEST |
| 690 | 1 | 0 | |a THIRD LEVEL |
| 690 | 1 | 0 | |a TORQUE CURVES |
| 690 | 1 | 0 | |a BUTADIENE |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a CURING |
| 690 | 1 | 0 | |a SCATTERING |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a X RAY SCATTERING |
| 690 | 1 | 0 | |a RUBBER |
| 700 | 1 | |a Somoza, Alberto Horacio | |
| 700 | 1 | |a Marzocca, Angel José | |
| 700 | 1 | |a Torriani, I. | |
| 700 | 1 | |a Mansilla, Marcela Angela | |
| 773 | 0 | |d 2009 |g v. 47 |h pp. 2320-2327 |k n. 23 |p J Polym Sci Part B |x 08876266 |w (AR-BaUEN)CENRE-5763 |t Journal of Polymer Science, Part B: Polymer Physics | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-72449131831&doi=10.1002%2fpolb.21828&partnerID=40&md5=2ce04ba7f2eea28aefd4af1205da9d78 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1002/polb.21828 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_08876266_v47_n23_p2320_Salgueiro |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08876266_v47_n23_p2320_Salgueiro |y Registro en la Biblioteca Digital |
| 961 | |a paper_08876266_v47_n23_p2320_Salgueiro |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 83973 | ||