Striped, bioactive Ce-TiO2 materials with peroxynitrite- scavenging activity
Controlling aligned fiber micro-architectures to simulate the extracellular matrix for inducing important biological functions is a key challenge with regard to successful tissue regeneration. Here we present a bottom-up microemulsion-mediated strategy to obtain highly bioactive and biocompatible, s...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
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2014
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| LEADER | 10606caa a22012857a 4500 | ||
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| 001 | PAPER-23876 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205538.0 | ||
| 008 | 190411s2014 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84892952171 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JMCBD | ||
| 100 | 1 | |a Gravina, A.N. | |
| 245 | 1 | 0 | |a Striped, bioactive Ce-TiO2 materials with peroxynitrite- scavenging activity |
| 260 | |c 2014 | ||
| 270 | 1 | 0 | |m Messina, P.V.; Department of Chemistry, INQUISUR-CONICET, Universidad Nacional Del sur, 8000, Bahía Blanca, Argentina; email: pmessina@uns.edu.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Controlling aligned fiber micro-architectures to simulate the extracellular matrix for inducing important biological functions is a key challenge with regard to successful tissue regeneration. Here we present a bottom-up microemulsion-mediated strategy to obtain highly bioactive and biocompatible, striped Ce-TiO2 nano-crystalline superstructures with ONOO - scavenging activity. The employment of a bulkier organic ceria precursor in the material synthesis has several concurrent effects: (I) influencing the interfacial microemulsion droplet elasticity to create an aligned distribution of prismatic anatase nanoparticles causing the final lined morphology, (II) stabilizing the anatase active phase in a fine dispersed state and improving its resistance to the thermal anatase-rutile conversion, (III) indirectly favoring the rapid formation on the material surface of a hydroxyapatite layer composed of sphere-like globules of 3-5 μm in diameter essential for bone-bonding, and finally (IV) accelerating the ONOO- degradation into less harmful species NO2- and O 2. © The 2014 Royal Society of Chemistry. |l eng | |
| 593 | |a Department of Chemistry, INQUISUR-CONICET, Universidad Nacional Del sur, 8000, Bahía Blanca, Argentina | ||
| 593 | |a Soft Matter and Molecular Biophysics Group, Department of Applied Physics, University of Santiago de Compostela, Santiago de Compostela, 15782, Spain | ||
| 593 | |a Department of Biology, Biochemistry and Pharmacy, Universidad Nacional Del sur, 8000, Bahía Blanca, Argentina | ||
| 593 | |a Department of Inorganic Chemistry, Analytics and Physical Chemistry, INQUIMAE, Universidad de Buenos Aires, Pabellón II, Buenos Aires, C1428EHA, Argentina | ||
| 690 | 1 | 0 | |a ANATASE NANOPARTICLES |
| 690 | 1 | 0 | |a BIOLOGICAL FUNCTIONS |
| 690 | 1 | 0 | |a EXTRACELLULAR MATRICES |
| 690 | 1 | 0 | |a HYDROXYAPATITE LAYERS |
| 690 | 1 | 0 | |a MATERIAL SURFACE |
| 690 | 1 | 0 | |a MATERIAL SYNTHESIS |
| 690 | 1 | 0 | |a MICRO ARCHITECTURES |
| 690 | 1 | 0 | |a SCAVENGING ACTIVITIES |
| 690 | 1 | 0 | |a BIOCOMPATIBILITY |
| 690 | 1 | 0 | |a ELASTICITY |
| 690 | 1 | 0 | |a MICROEMULSIONS |
| 690 | 1 | 0 | |a OXIDE MINERALS |
| 690 | 1 | 0 | |a SYNTHESIS (CHEMICAL) |
| 690 | 1 | 0 | |a TITANIUM DIOXIDE |
| 700 | 1 | |a Ruso, J.M. | |
| 700 | 1 | |a Laiuppa, J.A. | |
| 700 | 1 | |a Santillán, G.E. | |
| 700 | 1 | |a Marco-Brown, J.L. | |
| 700 | 1 | |a D'Elia, N.L. | |
| 700 | 1 | |a Messina, P.V. | |
| 773 | 0 | |d 2014 |g v. 2 |h pp. 834-845 |k n. 7 |p J. Mater. Chem. B |x 20507518 |t Journal of Materials Chemistry B | |
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| 856 | 4 | 0 | |u https://doi.org/10.1039/c3tb21556c |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_20507518_v2_n7_p834_Gravina |y Handle |
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