Viscosity and glass transition temperature of aqueous mixtures of trehalose with borax and sodium chloride

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The glass transition temperature (Tg) and viscosity of aqueous trehalose and its mixtures with either NaCl or Na2B4O7 (borax) have been measured over a wide range of concentration. Borax and sodium chloride increase the viscosity and Tg′ of aqueous trehalose. Although the presence of ionic charges m...

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Autor principal: Miller, D.P
Otros Autores: De Pablo, J.J, Corti, H.R
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1999
Acceso en línea:Registro en Scopus
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100 1 |a Miller, D.P. 
245 1 0 |a Viscosity and glass transition temperature of aqueous mixtures of trehalose with borax and sodium chloride 
260 |c 1999 
270 1 0 |m Miller, D.P.; Department of Chemical Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706, United States; email: depablo@engr.wisc.edu 
506 |2 openaire  |e Política editorial 
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520 3 |a The glass transition temperature (Tg) and viscosity of aqueous trehalose and its mixtures with either NaCl or Na2B4O7 (borax) have been measured over a wide range of concentration. Borax and sodium chloride increase the viscosity and Tg′ of aqueous trehalose. Although the presence of ionic charges may partly explain some of the observed effects, it is clear that ionic solutes that form complexes with trehalose lead to a greater increase in Tg. The viscosity of supercooled aqueous mixtures was measured at several temperatures, most of them above the so-called crossover temperature, Tg′, where a change in the dynamics of relaxation processes is expected. The viscosities of all the binary and ternary mixtures exhibit the same temperature dependence when the temperature is scaled according to the Tg values; a change in the slope of the linearized WLF representation is observed at a temperature close to 1.27g. Above this temperature, a power law expression provides a similar description of the temperature dependence of viscosity as the WLF equation, the former having a physical justification in the mode coupling theory. © 1999 American Chemical Society.  |l eng 
593 |a Department of Chemical Engineering, University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706, United States 
593 |a Institute de Química Física de Materiales, Ambiente Y Energía, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina 
593 |a Unidad de Actividad Química, Comisión Nacional de Energía Atómica, Av. Libertador 8250, 1429 Buenos Aires, Argentina 
700 1 |a De Pablo, J.J. 
700 1 |a Corti, H.R. 
773 0 |d 1999  |g v. 103  |h pp. 10243-10249  |k n. 46  |p J. Phys. Chem. B  |x 15206106  |w (AR-BaUEN)CENRE-5879  |t Journal of Physical Chemistry B 
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856 4 0 |u https://hdl.handle.net/20.500.12110/paper_15206106_v103_n46_p10243_Miller  |y Handle 
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