Excitation energy transfer and trapping in dye-loaded solid particles

The photophysics of several systems composed of a single dye or pairs of dyes attached to solid particles has been studied in the dry solid state at high dye concentrations taking into account light scattering and inner filter effects. Interaction among dye molecules and singlet-singlet energy trans...

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Autor principal: Rodríguez, H.B
Otros Autores: San Román, E.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Blackwell Publishing Inc. 2008
Acceso en línea:Registro en Scopus
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100 1 |a Rodríguez, H.B. 
245 1 0 |a Excitation energy transfer and trapping in dye-loaded solid particles 
260 |b Blackwell Publishing Inc.  |c 2008 
270 1 0 |m San Román, E.; Ciudad Universitaria, Pabellón II, C1428EHA Buenos Aires, Argentina; email: esr@qi.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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504 |a Lagorio, M.G., Dicelio, L.E., Litter, M.I., San Román, E., Modeling of fluorescence quantum yields of supported dyes. aluminium carboxyphthalocyanine on cellulose (1998) J. Chem. Soc., Faraday Trans., 94, pp. 419-425. , & 
504 |a Rodríguez, H.B., Lagorio, M.G., San Román, E., Rose Bengal adsorbed on microgranular cellulose: Evidence on fluorescent dimers (2004) Photochem. Photobiol. Sci., 3, pp. 674-680. , & 
504 |a Lagorio, M.G., San Román, E., Zeug, A., Photophysics on surfaces: Absorption and luminescence properties of pheophorbide-a on cellulose (2001) Phys. Chem. Chem. Phys., 3, pp. 1524-1529 
504 |a Iriel, A., Lagorio, M.G., Dicelio, L.E., San Román, E., Photophysics of supported dyes: Phthalocyanines on salinized silica (2002) Phys. Chem. Chem. Phys., 4, pp. 224-231. , & 
504 |a Rodríguez, H.B., Iriel, A., San Román, E., Energy transfer among dyes on particulate solids (2006) Photochem. Photobiol., 82, pp. 200-207. , & 
504 |a Rodríguez, H.B., San Román, E., Energy transfer from chemically attached rhodamine 101 to adsorbed methylene blue on microcrystalline cellulose particles (2007) Photochem. Photobiol., 83, pp. 547-555. , & 
504 |a Mirenda, M., Lagorio, M.G., San Román, E., Photophysics on surfaces. Determination of absolute fluorescence quantum yields from reflectance spectra (2004) Langmuir, 20, pp. 3690-3697. , & 
504 |a Vieira Ferreira, L.F., Garcia, A.R., Rosário Freixo, M., Costa, S.M.B., Photochemistry on surfaces: Solvent-matrix effect on the swelling of cellulose (1993) J. Chem. Soc. Faraday Trans., 89, pp. 1937-1944. , & 
504 |a Itoh, K., Chiyokawa, Y., Nakao, M., Honda, K., Fluorescence quenching processes of rhodamine B in oxide semiconductors and light-harvesting action of its dimers (1984) J. Am. Chem. Soc., 106, pp. 1620-1627. , & 
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520 3 |a The photophysics of several systems composed of a single dye or pairs of dyes attached to solid particles has been studied in the dry solid state at high dye concentrations taking into account light scattering and inner filter effects. Interaction among dye molecules and singlet-singlet energy transfer are relevant in these conditions, as has been demonstrated for pairs of dyes with suitable spectral overlap. For single dyes, after correction for radiative energy transfer, fluorescence quenching is observed as the surface concentration increases. This effect is explained by two different trapping models. Irrespective of the nature of the traps, concentration quenching may be of static (trap absorption) and dynamic (energy transfer) nature. The unraveling of energy trapping mechanisms is a key to the development of efficient photoactive solid materials. © 2008 New York Academy of Sciences.  |l eng 
593 |a INQUIMAE/DQIAYQF, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina 
593 |a Ciudad Universitaria, Pabellón II, C1428EHA Buenos Aires, Argentina 
690 1 0 |a DYE AGGREGATION 
690 1 0 |a ENERGY TRAPPING 
690 1 0 |a QUENCHING RADIUS 
690 1 0 |a SOLID PARTICLES 
690 1 0 |a DYE 
690 1 0 |a ABSORPTION 
690 1 0 |a CONFERENCE PAPER 
690 1 0 |a ENERGY TRANSFER 
690 1 0 |a ENERGY TRAPPING 
690 1 0 |a FLUORESCENCE ANALYSIS 
690 1 0 |a LIGHT SCATTERING 
690 1 0 |a MOLECULAR INTERACTION 
690 1 0 |a PHOTOCHEMICAL QUENCHING 
690 1 0 |a RADIATION ENERGY 
690 1 0 |a SOLID STATE 
700 1 |a San Román, E. 
773 0 |d Blackwell Publishing Inc., 2008  |g v. 1130  |h pp. 247-252  |p Ann. New York Acad. Sci.  |x 00778923  |w (AR-BaUEN)CENRE-1541  |t Annals of the New York Academy of Sciences 
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