Analysis of network structure formed in styrene-butadiene rubber cured with sulfur/TBBS system

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Several styrene-butadiene rubber (SBR) compounds were prepared with different cure systems based on sulfur and TBBS (N-i-butyl-2-benzothiazole sulfenamide), varying the amount of sulfur and accelerator between 0.5 and 2.5 phr in the formulation. Torque curves, measured with a moving die rheometer at...

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Detalles Bibliográficos
Autor principal: Marzocca, Angel José
Otros Autores: Mansilla, Marcela Angela
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2007
Acceso en línea:Registro en Scopus
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100 1 |a Marzocca, Angel José 
245 1 0 |a Analysis of network structure formed in styrene-butadiene rubber cured with sulfur/TBBS system 
260 |c 2007 
270 1 0 |m Marzocca, A.J.; Departamento de Física, Facultad de Ciencias Exactas y Naturales, LPMPyMC, Pabellón 1, 1428 Buenos Aires, Argentina; email: marzo@df.uba.ar 
504 |a Coran, A.Y., (1994) Science and Technology of Rubber, p. 339. , Mark, J. E, Erman, B, Eirich, F. R, Eds, Academic Press: San Diego, CA 
504 |a Akiba, M., Hahim, A.S., (1977) Prog Polym Sci, 22, p. 475 
504 |a Marzocca, A.J., Cerveny, S., Salgueiro, W., Somoza, A., Gonzalez, L., (2002) Phys Rev E, 65, p. 021801 
504 |a Salgueiro, W., Marzocca, A., Somoza, A., Consolati, G., Cerveny, S., Quasso, F., Goyanes, S., (2004) Polymer, 45, p. 6037 
504 |a Marzocca, A.J., Goyanes, S., (2004) J Appl Polym Sci, 91, p. 2601 
504 |a Marzocca, A.J., Mansilla, M.A., (2006) J Appl Polym Sci, 101, p. 35 
504 |a Aprem, A.S., Joseph, K., Thomas, S., (2005) Rubber Chem Technol, 78, p. 458 
504 |a Layer, R., (1992) Rubber Chem Technol, 65, p. 211 
504 |a Layer, R., (1992) Rubber Chem Technol, 65, p. 822 
504 |a Pellicioli, L., Mowdood, S.K., Negroni, F., Parker, D.D., Koenig, J.L., (2002) Rubber Chem Technol, 75, p. 1 
504 |a Flory, P.J., Rehner, J., (1943) J Chem Phys, 11, p. 512 
504 |a Flory, P.J., Rehner, J., (1943) J Chem Phys, 11, p. 521 
504 |a Mark, J.E., Erman, B., (1988) Rubberlike Elasticity: A Molecular Primer, p. 51. , Wiley: New York 
504 |a Cunneen, J.I., Russell, R.M., (1970) Rubber Chem Technol, 43, p. 1215 
504 |a Mathew, G., Pillai, P.V., Kuriakose, A.P., (1992) Rubber Chem Technol, 65, p. 227 
504 |a Levin, V.Y., Kim, S.H., Isayev, A.I., (1997) Rubber Chem Technol, 70, p. 641 
504 |a Kiroski, D.; Sims, J.; Packham, D. E. Kautsch Gummi Kunststoffe 1997, 50, 716; Lide, D.R., CRC, E., (1997) Handbook of Chemistry and Physics, pp. 3-55. , 78th ed, CRC Press: New York 
504 |a Deng, J.S., Isayev, I., (1991) Rubber Chem Technol, 64, p. 296 
504 |a Gronski, W., Hoffmann, V., Simon, G., Wutzler, A., Straube, E., (1991) Rubber Chem Technol, 65, p. 63 
504 |a Hagen, R., Salmén, L., Stenberg, B., (1997) J Polym Sci, Part B: Polym Phys 1996, p. 34 
504 |a Grest, G.S., Pütz, M., Everaers, R., Kremer, K., (2000) J Non-Cryst Solids, 274, p. 129 
506 |2 openaire  |e Política editorial 
520 3 |a Several styrene-butadiene rubber (SBR) compounds were prepared with different cure systems based on sulfur and TBBS (N-i-butyl-2-benzothiazole sulfenamide), varying the amount of sulfur and accelerator between 0.5 and 2.5 phr in the formulation. Torque curves, measured with a moving die rheometer at temperatures at 433 K, were used to characterize the vulcanization. The time to achieve the maximum torque, t100%, was evaluated for each sample, and this time was set to vulcanize sheets at 433 K. The density and type of elastically active crosslinks of each cured sample were evaluated by means of swelling measurements and were related to the vulcanizing system. Finally, the rheometer data were analyzed considering the network structure formed during vulcanization. © 2006 Wiley Periodicals, Inc.  |l eng 
593 |a Departamento de Física, Facultad de Ciencias Exactas y Naturales, LPMPyMC, Pabellón 1, 1428 Buenos Aires, Argentina 
690 1 0 |a CROSSLINK TYPES 
690 1 0 |a STYRENE-BUTADIENE RUBBER 
690 1 0 |a VULCANIZATION 
690 1 0 |a BUTADIENE 
690 1 0 |a CRYSTAL STRUCTURE 
690 1 0 |a ELASTICITY 
690 1 0 |a NITROGEN COMPOUNDS 
690 1 0 |a RUBBER 
690 1 0 |a VULCANIZATION 
690 1 0 |a CROSSLINK TYPES 
690 1 0 |a DIE RHEOMETER 
690 1 0 |a NETWORK STRUCTURE 
690 1 0 |a STYRENE-BUTADIENE RUBBER (SBR) COMPOUNDS 
690 1 0 |a STYRENE 
690 1 0 |a CROSS LINKING 
690 1 0 |a ELASTIC PROPERTY 
690 1 0 |a POLYBUTADIENE 
690 1 0 |a POLYSTYRENE 
690 1 0 |a SWELLING 
690 1 0 |a SYNTHETIC RUBBER 
700 1 |a Mansilla, Marcela Angela 
773 0 |d 2007  |g v. 103  |h pp. 1105-1112  |k n. 2  |p J. Appl. Polym. Sci.  |x 00218995  |w (AR-BaUEN)CENRE-330  |t Journal of Applied Polymer Science 
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