Accelerator adsorption onto carbon nanotubes surface ffects the vulcanization process of styrene-butadiene rubber composites

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The multiwalled carbon nanotubes (MWCNT) filled styrene-butadiene rubber (SBR) composites were prepared by incorporating MWCNT in a SBR/toluene solution and subsequently evaporating the solvent. These composites have shown a significant improvement in Young's modulus and tensile strength with r...

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Autor principal: De Falco, A.
Otros Autores: Marzocca, Angel José, Corcuera, M.A, Eceiza, A., Mondragon, Iñaki, Rubiolo, Gerardo Héctor, Goyanes, Silvia Nair
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: John Wiley and Sons Inc. 2009
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Acceso en línea:Registro en Scopus
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100 1 |a De Falco, A. 
245 1 0 |a Accelerator adsorption onto carbon nanotubes surface ffects the vulcanization process of styrene-butadiene rubber composites 
260 |b John Wiley and Sons Inc.  |c 2009 
270 1 0 |m Goyanes, S.; Laboratorio de Polímeros y Materiales Compuestos, FCEyN, Univ. Nac. de Buenos Aires. Pabellon, 1 Ciudad Universitaria, Buenos Aires 1424, Argentina; email: goyanes@df.uba.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a The multiwalled carbon nanotubes (MWCNT) filled styrene-butadiene rubber (SBR) composites were prepared by incorporating MWCNT in a SBR/toluene solution and subsequently evaporating the solvent. These composites have shown a significant improvement in Young's modulus and tensile strength with respect to SBR gum without sacrificing high elongation at break. However, this improvement is less than expected at the higher filler content. Then, the influence of low concentrations of MWCNT on the vulcanization process of the SBR composites was studied by means of rheometer torque curves, swelling measurements, differential scanning calorimeter (DSC) analysis, and Fourier transform infrared (FTIR) spectroscopy. Also, their thermal degradation was studied by thermogravimetric analysis (TGA). It has been noticed that MWCNT affects the cure kinetics of SBR gum matrix reducing all parameters, i.e., the total heat rate and order of the reaction, scorch delay, maximum torque, and crosslink density. This effect increases as MWCNT content does, and it was attributed to the adsorption of the accelerator employed in the vulcanization (N-tert-butyl-benzothiazole-2- sulfenamide) onto the MWCNT surface. © 2009 Wiley Periodicals, Inc.  |l eng 
593 |a Laboratorio de Polímeros y Materiales Compuestos, FCEyN, Univ. Nac. de Buenos Aires. Pabellon, 1 Ciudad Universitaria, Buenos Aires 1424, Argentina 
593 |a 'Materials + Technologies' Group, Escuela Politecnica, Dpto. Ingeniería Química y M. Ambiente, Universidad Páis Vasco, Donostia-San Sebastián, Spain 
593 |a Unidad de Actividad Materiales, Comisión Nacional de Energía Atómica (CNEA - CAC), Avda Gral Paz 1499, B1650KNA, San Martín, Argentina 
593 |a CONICET, Consejo Nacional de Investigaciones Científicas y Tecnólogicas, Argentina 
650 1 7 |2 spines  |a CARBON 
690 1 0 |a CARBON NANOTUBES 
690 1 0 |a ELASTOMERS 
690 1 0 |a NANOCOMPOSITES 
690 1 0 |a NANOTECHNOLOGY 
690 1 0 |a VULCANIZATION 
690 1 0 |a BUTADIENE 
690 1 0 |a CARBON NANOTUBES 
690 1 0 |a DIFFERENTIAL SCANNING CALORIMETRY 
690 1 0 |a ELASTIC MODULI 
690 1 0 |a ELASTOMERS 
690 1 0 |a FOURIER TRANSFORM INFRARED SPECTROSCOPY 
690 1 0 |a NANOCOMPOSITES 
690 1 0 |a NANOTECHNOLOGY 
690 1 0 |a REACTION KINETICS 
690 1 0 |a RUBBER 
690 1 0 |a STYRENE 
690 1 0 |a TENSILE STRENGTH 
690 1 0 |a THERMOGRAVIMETRIC ANALYSIS 
690 1 0 |a VULCANIZATION 
690 1 0 |a YARN 
690 1 0 |a CROSS-LINK DENSITIES 
690 1 0 |a DIFFERENTIAL SCANNING CALORIMETER ANALYSIS 
690 1 0 |a FILLER CONTENTS 
690 1 0 |a LOW CONCENTRATIONS 
690 1 0 |a MULTIWALLED CARBON NANOTUBE (MWCNT) 
690 1 0 |a STYRENE BUTADIENE RUBBER 
690 1 0 |a SWELLING MEASUREMENTS 
690 1 0 |a VULCANIZATION PROCESS 
690 1 0 |a MULTIWALLED CARBON NANOTUBES (MWCN) 
690 1 0 |a ADSORPTION 
690 1 0 |a COMPOSITE 
690 1 0 |a CONCENTRATION 
690 1 0 |a CROSS LINKING 
690 1 0 |a FILLING MATERIAL 
690 1 0 |a NANOTUBE 
690 1 0 |a SOLVENT 
690 1 0 |a SWELLING 
690 1 0 |a TENSILE PROPERTY 
690 1 0 |a TORQUE 
690 1 0 |a YOUNG MODULUS 
700 1 |a Marzocca, Angel José 
700 1 |a Corcuera, M.A. 
700 1 |a Eceiza, A. 
700 1 |a Mondragon, Iñaki 
700 1 |a Rubiolo, Gerardo Héctor 
700 1 |a Goyanes, Silvia Nair 
773 0 |d John Wiley and Sons Inc., 2009  |g v. 113  |h pp. 2851-2857  |k n. 5  |p J. Appl. Polym. Sci.  |x 00218995  |w (AR-BaUEN)CENRE-330  |t Journal of Applied Polymer Science 
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856 4 0 |u https://doi.org/10.1002/app.30261  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00218995_v113_n5_p2851_DeFalco  |y Handle 
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