Block copolymer concentration gradient and solvent effects on nanostructuring of thin epoxy coatings modified with epoxidized styrene-butadiene-styrene block copolymers

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The gradient on block copolymer concentration through film thickness as well as the effects of casting solvents used on the nanostructuring of a thermosetting epoxy coating modified with an epoxidized poly(styrene-b- butadiene-b-styrene) (SBS) triblock copolymer was studied by means of atomic force...

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Autor principal: Ramos, J.A
Otros Autores: Espósito, L.H, Fernández, R., Zalakain, I., Goyanes, Silvia Nair, Avgeropoulos, A., Zafeiropoulos, N.E, Kortaberria, G., Mondragon, Iñaki
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2012
Acceso en línea:Registro en Scopus
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100 1 |a Ramos, J.A. 
245 1 0 |a Block copolymer concentration gradient and solvent effects on nanostructuring of thin epoxy coatings modified with epoxidized styrene-butadiene-styrene block copolymers 
260 |c 2012 
270 1 0 |m Mondragon, I.; Department of Chemical and Environmental Engineering, Polytechnic School, University of the Basque Country, Pza. Europa 1, 20018 Donostia-San Sebastian, Spain; email: inaki.mondragon@ehu.es 
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506 |2 openaire  |e Política editorial 
520 3 |a The gradient on block copolymer concentration through film thickness as well as the effects of casting solvents used on the nanostructuring of a thermosetting epoxy coating modified with an epoxidized poly(styrene-b- butadiene-b-styrene) (SBS) triblock copolymer was studied by means of atomic force microscopy and attenuated total reflectance infrared spectroscopy. Thin coating films based on a commercial epoxy-amine formulation consisting of diglycidyl ether of bisphenol A and a low-temperature fast curing amine were modified with several amounts of epoxidized SBS triblock copolymer. Toluene and a mixture of tetrahydrofuran and N,N-dimethylformamide were used as casting solvents. With epoxidation degrees higher than 45 mol % of polybutadiene block nanostructuring was achieved. Fast curing rate of the epoxy/amine system and the comparatively slow evaporation rate of the casting solvent led to a gradient of morphologies through the film cross section owing to the coalescence of small micelles into larger micellar domains in the case of low block copolymer content. For these reasons, different morphologies were also obtained in the midtransverse section of a film with variable thickness. Finally, pseudolamellar nanostructure at high copolymer contents was achieved as confirmed by parallel and perpendicular cuttings to the air/polymer interface. © 2012 American Chemical Society.  |l eng 
593 |a Department of Chemical and Environmental Engineering, Polytechnic School, University of the Basque Country, Pza. Europa 1, 20018 Donostia-San Sebastian, Spain 
593 |a Dep Física, FCEN-UBA, Ciudad Universitaria, Pab. 1, C1428EGA, Ciudad Autónoma de Buenos Aires, Argentina 
593 |a Department of Materials Science and Engineering, University of Ioannina, University Campus, Dourouti, 45110 Ioannina, Greece 
690 1 0 |a ATTENUATED TOTAL REFLECTANCE INFRARED SPECTROSCOPY 
690 1 0 |a COPOLYMER CONCENTRATION 
690 1 0 |a CROSS SECTION 
690 1 0 |a DIGLYCIDYL ETHER OF BISPHENOL-A 
690 1 0 |a EPOXY COATINGS 
690 1 0 |a EPOXY-AMINE 
690 1 0 |a FAST CURING 
690 1 0 |a LOW TEMPERATURES 
690 1 0 |a N ,N-DIMETHYLFORMAMIDE 
690 1 0 |a NANO-STRUCTURING 
690 1 0 |a SLOW EVAPORATION 
690 1 0 |a SMALL MICELLES 
690 1 0 |a SOLVENT EFFECTS 
690 1 0 |a STYRENE BUTADIENE STYRENES 
690 1 0 |a TETRA-HYDROFURAN 
690 1 0 |a THERMOSETTING EPOXY 
690 1 0 |a THIN COATING FILMS 
690 1 0 |a VARIABLE THICKNESS 
690 1 0 |a ATOMIC FORCE MICROSCOPY 
690 1 0 |a BUTADIENE 
690 1 0 |a COALESCENCE 
690 1 0 |a COATINGS 
690 1 0 |a CONCRETE BEAMS AND GIRDERS 
690 1 0 |a DIMETHYLFORMAMIDE 
690 1 0 |a EPOXY RESINS 
690 1 0 |a ETHERS 
690 1 0 |a INFRARED SPECTROSCOPY 
690 1 0 |a MORPHOLOGY 
690 1 0 |a ORGANIC COMPOUNDS 
690 1 0 |a ORGANIC SOLVENTS 
690 1 0 |a POLYBUTADIENES 
690 1 0 |a SOLVENTS 
690 1 0 |a STYRENE 
690 1 0 |a THERMOSETS 
690 1 0 |a TOLUENE 
690 1 0 |a BLOCK COPOLYMERS 
700 1 |a Espósito, L.H. 
700 1 |a Fernández, R. 
700 1 |a Zalakain, I. 
700 1 |a Goyanes, Silvia Nair 
700 1 |a Avgeropoulos, A. 
700 1 |a Zafeiropoulos, N.E. 
700 1 |a Kortaberria, G. 
700 1 |a Mondragon, Iñaki 
773 0 |d 2012  |g v. 45  |h pp. 1483-1491  |k n. 3  |p Macromolecules  |x 00249297  |w (AR-BaUEN)CENRE-21  |t Macromolecules 
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