Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution

The thermal decomposition reaction of acetone cyclic diperoxide (ACDP) in 1-octanol (OCT) solution, at the temperatures and initial concentration ranges of 130° -166 ºC and (0.94-3.00) x 10-2 mol/L , respectively, follows a pseudo-first order kinetic law. Acetone is the main organic decomposition pr...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Leiva, Laura A. C., Jorge, Nelly L., Romero, Jorge M., Cafferata, Lázaro F. R., Gómez Vara, Manuel E., Castro, Eduardo Alberto
Formato: Articulo
Lenguaje:Inglés
Publicado: 2008
Materias:
Química
tetroxane
thermal decomposition
ACDP
diperoxide
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/116694
https://www.aqa.org.ar/images/anales/pdf9612/9612art11.pdf
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-116694
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
tetroxane
thermal decomposition
ACDP
diperoxide
spellingShingle Química
tetroxane
thermal decomposition
ACDP
diperoxide
Leiva, Laura A. C.
Jorge, Nelly L.
Romero, Jorge M.
Cafferata, Lázaro F. R.
Gómez Vara, Manuel E.
Castro, Eduardo Alberto
Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
topic_facet Química
tetroxane
thermal decomposition
ACDP
diperoxide
description The thermal decomposition reaction of acetone cyclic diperoxide (ACDP) in 1-octanol (OCT) solution, at the temperatures and initial concentration ranges of 130° -166 ºC and (0.94-3.00) x 10-2 mol/L , respectively, follows a pseudo-first order kinetic law. Acetone is the main organic decomposition product observed. The activation parameters values of the initial reaction step (ΔH# = 25.8 ± 0.3 kcal/mol; ΔS# = -19.1 ± 0.6 cal/mol K; Ea = 26.6 ± 0.3 kcal/mol), support a reaction mechanism which includes a homolytic rupture of one peroxidic bond of the ACDP molecule with participation of the solvent and involving a biradical intermediate.
format Articulo
Articulo
author Leiva, Laura A. C.
Jorge, Nelly L.
Romero, Jorge M.
Cafferata, Lázaro F. R.
Gómez Vara, Manuel E.
Castro, Eduardo Alberto
author_facet Leiva, Laura A. C.
Jorge, Nelly L.
Romero, Jorge M.
Cafferata, Lázaro F. R.
Gómez Vara, Manuel E.
Castro, Eduardo Alberto
author_sort Leiva, Laura A. C.
title Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
title_short Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
title_full Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
title_fullStr Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
title_full_unstemmed Thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
title_sort thermal decomposition of the acetone cyclic diperoxide in 1-octanol solution
publishDate 2008
url http://sedici.unlp.edu.ar/handle/10915/116694
https://www.aqa.org.ar/images/anales/pdf9612/9612art11.pdf
work_keys_str_mv AT leivalauraac thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
AT jorgenellyl thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
AT romerojorgem thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
AT cafferatalazarofr thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
AT gomezvaramanuele thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
AT castroeduardoalberto thermaldecompositionoftheacetonecyclicdiperoxidein1octanolsolution
bdutipo_str Repositorios
_version_ 1764820446354604032

Ejemplares similares