Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina

To detect volatile organic compounds (VOCs) in indoor air in small enterprises in La Plata city and surrounding areas, sampling was conducted using passive diffusion monitors (3M-3500) and analysis of the samples were performed byCG-FID. Analytic methodology was optimized for 23 VOCs (n-alkanes, cyc...

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Autores principales: Colman Lerner, Jorge Esteban, Sanchez, Erica Yanina, Sambeth, Jorge Enrique, Porta, Atilio Andrés
Formato: Articulo
Lenguaje:Inglés
Publicado: 2012
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119348
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id I19-R120-10915-119348
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Monitoring
VOCs
Recovery factor Indoor air quality
Health risk assessment
spellingShingle Química
Monitoring
VOCs
Recovery factor Indoor air quality
Health risk assessment
Colman Lerner, Jorge Esteban
Sanchez, Erica Yanina
Sambeth, Jorge Enrique
Porta, Atilio Andrés
Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
topic_facet Química
Monitoring
VOCs
Recovery factor Indoor air quality
Health risk assessment
description To detect volatile organic compounds (VOCs) in indoor air in small enterprises in La Plata city and surrounding areas, sampling was conducted using passive diffusion monitors (3M-3500) and analysis of the samples were performed byCG-FID. Analytic methodology was optimized for 23 VOCs (n-alkanes, cycloalkanes, aromatic and chlorinated compounds, ketones and terpenes compounds) by determining the recovery factor and detection limit for each analyte. Different recovery values were obtained by desorbing with a mixture of dichloromethane: methanol (50:50), with a standard deviation lower than 5%. Enterprise analyzed included chemical analysis laboratories, sewing workrooms, electromechanical repair and car painting centers, take away food shops, and a photocopy center. The highest levels of VOCs were found to be in electromechanical repair and car painting centers (hexane, BTEX, CHCl3, CCl4) followed by chemical analysis laboratories and sewing workrooms. Cancer and noncancer risks were assessed using conventional approaches (HQ and LCR, US EPA) using the benzene, trichloroethylene, chloroform for cancer risk, and toluene, xylene and n-hexane, for noncancer risks as markers. The results showed different LCR for benzene and trichloroethylene between the different indoor environments analyzed (electromechanical repair and car painting center[others) and chloroform (laboratory >- others), but comparing with the results obtained by other research, are in similar order of magnitude for equivalents activities. Similar finding were founded for HQ. Comparing these results with the worker protection legislation the electromechanical repair and car painting center and chemical analysis laboratories are close to the limits advised by OSHA and ACGIH. These facts show the importance of the use of abatement technologies for the complete reduction of VOCs levels, to mitigate their impact in the worker’s health and their venting to the atmosphere.
format Articulo
Articulo
author Colman Lerner, Jorge Esteban
Sanchez, Erica Yanina
Sambeth, Jorge Enrique
Porta, Atilio Andrés
author_facet Colman Lerner, Jorge Esteban
Sanchez, Erica Yanina
Sambeth, Jorge Enrique
Porta, Atilio Andrés
author_sort Colman Lerner, Jorge Esteban
title Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
title_short Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
title_full Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
title_fullStr Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
title_full_unstemmed Characterization and health risk assessment of VOCs in occupational environments in Buenos Aires, Argentina
title_sort characterization and health risk assessment of vocs in occupational environments in buenos aires, argentina
publishDate 2012
url http://sedici.unlp.edu.ar/handle/10915/119348
work_keys_str_mv AT colmanlernerjorgeesteban characterizationandhealthriskassessmentofvocsinoccupationalenvironmentsinbuenosairesargentina
AT sanchezericayanina characterizationandhealthriskassessmentofvocsinoccupationalenvironmentsinbuenosairesargentina
AT sambethjorgeenrique characterizationandhealthriskassessmentofvocsinoccupationalenvironmentsinbuenosairesargentina
AT portaatilioandres characterizationandhealthriskassessmentofvocsinoccupationalenvironmentsinbuenosairesargentina
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