Synergistic Effects in the Inhibition of Copper Corrosion

Benzotriazole (BTA), thiourea (TU), and potassium ethylxanthate (KEX), behave as copper (Cu) corrosion inhibitors under certain conditions. These chemicals have been investigated to establish whether they provide synergistic effects. The Cu corrosion inhibition was followed through changes in electr...

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Autores principales: González, S., Laz, M. M., Souto, R. M., Salvarezza, Roberto Carlos, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1993
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/127514
https://onepetro.org/corrosion/article-abstract/116959/Synergistic-Effects-in-the-Inhibition-of-Copper?redirectedFrom=fulltext
Aporte de:
id I19-R120-10915-127514
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
benzotriazole
copper pitting
potassium ethylxanthate
synergistic inhibiting effects
thiourea
spellingShingle Ciencias Exactas
Química
benzotriazole
copper pitting
potassium ethylxanthate
synergistic inhibiting effects
thiourea
González, S.
Laz, M. M.
Souto, R. M.
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
Synergistic Effects in the Inhibition of Copper Corrosion
topic_facet Ciencias Exactas
Química
benzotriazole
copper pitting
potassium ethylxanthate
synergistic inhibiting effects
thiourea
description Benzotriazole (BTA), thiourea (TU), and potassium ethylxanthate (KEX), behave as copper (Cu) corrosion inhibitors under certain conditions. These chemicals have been investigated to establish whether they provide synergistic effects. The Cu corrosion inhibition was followed through changes in electrochemical characteristics. Cu specimens were tested at 25°C in two aggressive media, 0.1 M NaCl and 1 M NaClO<sub>4</sub>, using the linear potential sweep technique at 0.001 V s<sup>–1</sup> and by scanning electron microscopy of Cu specimens subjected to potentiodynamic and potentiostatic routines. A comparative behavior of the different substances for Cu was presented in the 6.6 ≤ pH ≤ 11 range. For KEX-BTA mixtures, synergistic inhibition effects were found in 0.1 M NaCl (7 ≤ pH ≤ 11). The apparent synergistic inhibition was explained tentatively by an increase in the compactness of the polymer-like passivating layer of KEX-Cu, which formed in the presence of BTA and Cl– ions.
format Articulo
Articulo
author González, S.
Laz, M. M.
Souto, R. M.
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
author_facet González, S.
Laz, M. M.
Souto, R. M.
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
author_sort González, S.
title Synergistic Effects in the Inhibition of Copper Corrosion
title_short Synergistic Effects in the Inhibition of Copper Corrosion
title_full Synergistic Effects in the Inhibition of Copper Corrosion
title_fullStr Synergistic Effects in the Inhibition of Copper Corrosion
title_full_unstemmed Synergistic Effects in the Inhibition of Copper Corrosion
title_sort synergistic effects in the inhibition of copper corrosion
publishDate 1993
url http://sedici.unlp.edu.ar/handle/10915/127514
https://onepetro.org/corrosion/article-abstract/116959/Synergistic-Effects-in-the-Inhibition-of-Copper?redirectedFrom=fulltext
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AT salvarezzarobertocarlos synergisticeffectsintheinhibitionofcoppercorrosion
AT arviaalejandrojorge synergisticeffectsintheinhibitionofcoppercorrosion
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