Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate

The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit...

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Autores principales: Baran, Enrique José, Parajón Costa, Beatriz Susana, Echeverría, Gustavo Alberto, Piro, Oscar Enrique
Formato: Articulo
Lenguaje:Inglés
Publicado: 2015
Materias:
Química
Thallium(I) acesulfamate
Synthesis
Crystal structure
IR spectra
Raman spectra
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/128456
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-128456
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Thallium(I) acesulfamate
Synthesis
Crystal structure
IR spectra
Raman spectra
spellingShingle Química
Thallium(I) acesulfamate
Synthesis
Crystal structure
IR spectra
Raman spectra
Baran, Enrique José
Parajón Costa, Beatriz Susana
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
topic_facet Química
Thallium(I) acesulfamate
Synthesis
Crystal structure
IR spectra
Raman spectra
description The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z = 4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed.
format Articulo
Articulo
author Baran, Enrique José
Parajón Costa, Beatriz Susana
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
author_facet Baran, Enrique José
Parajón Costa, Beatriz Susana
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
author_sort Baran, Enrique José
title Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
title_short Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
title_full Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
title_fullStr Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
title_full_unstemmed Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate
title_sort synthesis, structural and spectroscopic characterization of thallium(i) acesulfamate
publishDate 2015
url http://sedici.unlp.edu.ar/handle/10915/128456
work_keys_str_mv AT baranenriquejose synthesisstructuralandspectroscopiccharacterizationofthalliumiacesulfamate
AT parajoncostabeatrizsusana synthesisstructuralandspectroscopiccharacterizationofthalliumiacesulfamate
AT echeverriagustavoalberto synthesisstructuralandspectroscopiccharacterizationofthalliumiacesulfamate
AT pirooscarenrique synthesisstructuralandspectroscopiccharacterizationofthalliumiacesulfamate
bdutipo_str Repositorios
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