The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate

The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) A, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman s...

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Detalles Bibliográficos
Autores principales: Piro, Oscar Enrique, Baran, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1997
Materias:
Física
Ciencias Exactas
Bis(malonato)oxovanadiumt(lV)
crystal structure
IR and Raman spectra
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/141107
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-141107
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Física
Ciencias Exactas
Bis(malonato)oxovanadiumt(lV)
crystal structure
IR and Raman spectra
spellingShingle Física
Ciencias Exactas
Bis(malonato)oxovanadiumt(lV)
crystal structure
IR and Raman spectra
Piro, Oscar Enrique
Baran, Enrique José
The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
topic_facet Física
Ciencias Exactas
Bis(malonato)oxovanadiumt(lV)
crystal structure
IR and Raman spectra
description The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) A, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman spectra are also reported to attain a wider insight into the compound characteristics.
format Articulo
Articulo
author Piro, Oscar Enrique
Baran, Enrique José
author_facet Piro, Oscar Enrique
Baran, Enrique José
author_sort Piro, Oscar Enrique
title The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
title_short The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
title_full The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
title_fullStr The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
title_full_unstemmed The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate
title_sort crystal and molecular structure of ammonium-bis(malonato) oxovanadium(iv) dihydrate
publishDate 1997
url http://sedici.unlp.edu.ar/handle/10915/141107
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