Oxovanadium(IV) complexes of halogenated oxines

Six VO²⁺ complexes of 8-hydroxyquinoline (oxine) and of some of its mono- and dihalogenated derivatives have been prepared. The complex of 5-chloro-oxine is very unstable and oxidizes rapidly, generating a V(V) complex of stoichiometry VO(QCl)₂OH which could also be prepared in pure form. The infrar...

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Autores principales:	González Baró, Ana Cecilia, Baran, Enrique José
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	1997
Materias:	Química Vanadyl(IV) Oxine Halogenated oxines IR Magnetic susceptibilities Electronic spectra Solution behaviour
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/146077
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-146077
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Química Vanadyl(IV) Oxine Halogenated oxines IR Magnetic susceptibilities Electronic spectra Solution behaviour
spellingShingle	Química Vanadyl(IV) Oxine Halogenated oxines IR Magnetic susceptibilities Electronic spectra Solution behaviour González Baró, Ana Cecilia Baran, Enrique José Oxovanadium(IV) complexes of halogenated oxines
topic_facet	Química Vanadyl(IV) Oxine Halogenated oxines IR Magnetic susceptibilities Electronic spectra Solution behaviour
description	Six VO²⁺ complexes of 8-hydroxyquinoline (oxine) and of some of its mono- and dihalogenated derivatives have been prepared. The complex of 5-chloro-oxine is very unstable and oxidizes rapidly, generating a V(V) complex of stoichiometry VO(QCl)₂OH which could also be prepared in pure form. The infrared spectra of all complexes have been recorded and are discussed in detail. The complexes containing halogenated ligands appear as polymeric species, interacting through V=O...V=O bridges. The magnetic moments, investigated at room temperature, indicate completely quenched orbital contributions. The analysis of the electronic spectra reveals very complex solution behaviour including, oxidation phenomena, ligand loss, and interaction with the solvent.
format	Articulo Articulo
author	González Baró, Ana Cecilia Baran, Enrique José
author_facet	González Baró, Ana Cecilia Baran, Enrique José
author_sort	González Baró, Ana Cecilia
title	Oxovanadium(IV) complexes of halogenated oxines
title_short	Oxovanadium(IV) complexes of halogenated oxines
title_full	Oxovanadium(IV) complexes of halogenated oxines
title_fullStr	Oxovanadium(IV) complexes of halogenated oxines
title_full_unstemmed	Oxovanadium(IV) complexes of halogenated oxines
title_sort	oxovanadium(iv) complexes of halogenated oxines
publishDate	1997
url	http://sedici.unlp.edu.ar/handle/10915/146077
work_keys_str_mv	AT gonzalezbaroanacecilia oxovanadiumivcomplexesofhalogenatedoxines AT baranenriquejose oxovanadiumivcomplexesofhalogenatedoxines
bdutipo_str	Repositorios
_version_	1764820460556517377

Oxovanadium(IV) complexes of halogenated oxines

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