Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Fumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living)...

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Autores principales: Oberti, Tamara Gisela, Cortizo, María Susana
Formato: Articulo
Lenguaje:Inglés
Publicado: 2023
Materias:
Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/163969
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-163969
record_format dspace
spelling I19-R120-10915-1639692024-03-19T04:07:22Z http://sedici.unlp.edu.ar/handle/10915/163969 Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications Oberti, Tamara Gisela Cortizo, María Susana 2023-10 2024-03-18T17:16:31Z en Ciencias Exactas Química polyfumarate radical polymerization thermal properties tissue engineering energy applications Fumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living) are detailed and their characteristic kinetic parameters are shown. For example, the use of the initiator 2,2′-azobis(isobutyrate) (MAIB) allows to obtain polymers of higher molecular weight since it generates more stable primary radicals than those achieved with other azo initiators. The emergence of different controlled radical polymerization methodologies has resulted in the generation of new fumaric homo and copolymers with different properties. The structural characteristics of these materials analyzed by spectroscopic techniques and their relationship with properties in solutions, glass transition temperature, thermal stability and mechanical behavior are detailed in the present work. Finally, several biomedical and energy applications are described in which copolymers from fumaric and acrylic monomers were employed, combined or not with natural polymers to be used as scaffolds in the regeneration of bone and cartilage tissue, drug delivery systems, as flow or asphalt modifiers. From the complete reading of this review, it will be possible to achieve a global vision starting from the synthesis to the application of fumaric polymers in which the need of scaling this type of productions to reach specific industrial applications is visualized. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Articulo Articulo http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) application/pdf
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
spellingShingle Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
Oberti, Tamara Gisela
Cortizo, María Susana
Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
topic_facet Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
description Fumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living) are detailed and their characteristic kinetic parameters are shown. For example, the use of the initiator 2,2′-azobis(isobutyrate) (MAIB) allows to obtain polymers of higher molecular weight since it generates more stable primary radicals than those achieved with other azo initiators. The emergence of different controlled radical polymerization methodologies has resulted in the generation of new fumaric homo and copolymers with different properties. The structural characteristics of these materials analyzed by spectroscopic techniques and their relationship with properties in solutions, glass transition temperature, thermal stability and mechanical behavior are detailed in the present work. Finally, several biomedical and energy applications are described in which copolymers from fumaric and acrylic monomers were employed, combined or not with natural polymers to be used as scaffolds in the regeneration of bone and cartilage tissue, drug delivery systems, as flow or asphalt modifiers. From the complete reading of this review, it will be possible to achieve a global vision starting from the synthesis to the application of fumaric polymers in which the need of scaling this type of productions to reach specific industrial applications is visualized.
format Articulo
Articulo
author Oberti, Tamara Gisela
Cortizo, María Susana
author_facet Oberti, Tamara Gisela
Cortizo, María Susana
author_sort Oberti, Tamara Gisela
title Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_short Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_full Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_fullStr Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_full_unstemmed Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_sort homo- and copolymers based on dialkyl fumarates: a review on radical polymerization, properties, current and future applications
publishDate 2023
url http://sedici.unlp.edu.ar/handle/10915/163969
work_keys_str_mv AT obertitamaragisela homoandcopolymersbasedondialkylfumaratesareviewonradicalpolymerizationpropertiescurrentandfutureapplications
AT cortizomariasusana homoandcopolymersbasedondialkylfumaratesareviewonradicalpolymerizationpropertiescurrentandfutureapplications
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