Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from on...
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| Formato: | Artículo publishedVersion |
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2012
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_16005368_v68_n11_pm1377_Harvey_oai |
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I28-R145-paper_16005368_v68_n11_pm1377_Harvey_oai2024-08-16 Harvey, M.A. Suarez, S.A. Ibañez, A. Doctorovich, F. Baggio, R. 2012 The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn-O distances of 2.058(2) and 2.362(3)Å], while the two Zn-N bond distances are equal as imposed by symmetry [2.079(2)Å]. The crystal structure is supported by a number of weak C-H⋯O interactions and C-H⋯π contacts, with no π-π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. application/pdf http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar Acta Crystallogr. Sect. E Struct. Rep. Online 2012;68(11):m1377-m1378 data-to-parameter ratio = 14.6 mean ̄(C-C) = 0.004 Å R factor = 0.026 single-crystal X-ray study T = 295 K wR factor = 0.068 Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_16005368_v68_n11_pm1377_Harvey_oai |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-145 |
| collection |
Repositorio Digital de la Universidad de Buenos Aires (UBA) |
| topic |
data-to-parameter ratio = 14.6 mean ̄(C-C) = 0.004 Å R factor = 0.026 single-crystal X-ray study T = 295 K wR factor = 0.068 |
| spellingShingle |
data-to-parameter ratio = 14.6 mean ̄(C-C) = 0.004 Å R factor = 0.026 single-crystal X-ray study T = 295 K wR factor = 0.068 Harvey, M.A. Suarez, S.A. Ibañez, A. Doctorovich, F. Baggio, R. Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| topic_facet |
data-to-parameter ratio = 14.6 mean ̄(C-C) = 0.004 Å R factor = 0.026 single-crystal X-ray study T = 295 K wR factor = 0.068 |
| description |
The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn-O distances of 2.058(2) and 2.362(3)Å], while the two Zn-N bond distances are equal as imposed by symmetry [2.079(2)Å]. The crystal structure is supported by a number of weak C-H⋯O interactions and C-H⋯π contacts, with no π-π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors. |
| format |
Artículo Artículo publishedVersion |
| author |
Harvey, M.A. Suarez, S.A. Ibañez, A. Doctorovich, F. Baggio, R. |
| author_facet |
Harvey, M.A. Suarez, S.A. Ibañez, A. Doctorovich, F. Baggio, R. |
| author_sort |
Harvey, M.A. |
| title |
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| title_short |
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| title_full |
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| title_fullStr |
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| title_full_unstemmed |
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc |
| title_sort |
bis(acetato-κ2 o,o')(4,4′-dimethyl-2,2′- bipyridine-κ2 n,n')zinc |
| publishDate |
2012 |
| url |
http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_16005368_v68_n11_pm1377_Harvey_oai |
| work_keys_str_mv |
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| _version_ |
1809357027809427456 |