Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes

The inorganic nitrosyl (NO+) complexes [Fe(CN) 5NO]2-, [Ru(bpy)2 (NO)Cl]2+, and [IrCl5(NO)]- are useful reagents for the nitrosation of a variety of organic compounds, ranging from amines to the relatively inert alkenes. Regarding [IrCl5(NO)]-, its high electrophilicity and inertness define it as a...

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Detalles Bibliográficos
Autores principales:	Doctorovich, Fabio Ariel, Di Salvo, Florencia
Publicado:	2007
Materias:	inorganic compound nitroso derivative organic compound article chemical structure chemistry X ray crystallography Crystallography, X-Ray Inorganic Chemicals Models, Molecular Nitroso Compounds Organic Chemicals
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00014842_v40_n10_p985_Doctorovich http://hdl.handle.net/20.500.12110/paper_00014842_v40_n10_p985_Doctorovich
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00014842_v40_n10_p985_Doctorovich
record_format	dspace
spelling	paper:paper_00014842_v40_n10_p985_Doctorovich2025-07-30T17:05:19Z Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes Doctorovich, Fabio Ariel Di Salvo, Florencia inorganic compound nitroso derivative organic compound article chemical structure chemistry X ray crystallography Crystallography, X-Ray Inorganic Chemicals Models, Molecular Nitroso Compounds Organic Chemicals The inorganic nitrosyl (NO+) complexes [Fe(CN) 5NO]2-, [Ru(bpy)2 (NO)Cl]2+, and [IrCl5(NO)]- are useful reagents for the nitrosation of a variety of organic compounds, ranging from amines to the relatively inert alkenes. Regarding [IrCl5(NO)]-, its high electrophilicity and inertness define it as a unique reagent and provide a powerful synthetic route for the isolation and stabilization of coordinated nitroso compounds that are unstable in free form, such as S-nitrosothiols and primary nitrosamines. Related to the high electrophilicity of [IrCl5(NO)]-, an unusual behavior is described for its PPh4+ salt in the solid state, showing an electronic distribution represented by Ir IV-NO• instead of IrIII-NO+ (as for the K+ and Na+ salts). © 2007 American Chemical Society. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00014842_v40_n10_p985_Doctorovich http://hdl.handle.net/20.500.12110/paper_00014842_v40_n10_p985_Doctorovich
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	inorganic compound nitroso derivative organic compound article chemical structure chemistry X ray crystallography Crystallography, X-Ray Inorganic Chemicals Models, Molecular Nitroso Compounds Organic Chemicals
spellingShingle	inorganic compound nitroso derivative organic compound article chemical structure chemistry X ray crystallography Crystallography, X-Ray Inorganic Chemicals Models, Molecular Nitroso Compounds Organic Chemicals Doctorovich, Fabio Ariel Di Salvo, Florencia Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
topic_facet	inorganic compound nitroso derivative organic compound article chemical structure chemistry X ray crystallography Crystallography, X-Ray Inorganic Chemicals Models, Molecular Nitroso Compounds Organic Chemicals
description	The inorganic nitrosyl (NO+) complexes [Fe(CN) 5NO]2-, [Ru(bpy)2 (NO)Cl]2+, and [IrCl5(NO)]- are useful reagents for the nitrosation of a variety of organic compounds, ranging from amines to the relatively inert alkenes. Regarding [IrCl5(NO)]-, its high electrophilicity and inertness define it as a unique reagent and provide a powerful synthetic route for the isolation and stabilization of coordinated nitroso compounds that are unstable in free form, such as S-nitrosothiols and primary nitrosamines. Related to the high electrophilicity of [IrCl5(NO)]-, an unusual behavior is described for its PPh4+ salt in the solid state, showing an electronic distribution represented by Ir IV-NO• instead of IrIII-NO+ (as for the K+ and Na+ salts). © 2007 American Chemical Society.
author	Doctorovich, Fabio Ariel Di Salvo, Florencia
author_facet	Doctorovich, Fabio Ariel Di Salvo, Florencia
author_sort	Doctorovich, Fabio Ariel
title	Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
title_short	Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
title_full	Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
title_fullStr	Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
title_full_unstemmed	Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes
title_sort	performing organic chemistry with inorganic compounds: electrophilic reactivity of selected nitrosyl complexes
publishDate	2007
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00014842_v40_n10_p985_Doctorovich http://hdl.handle.net/20.500.12110/paper_00014842_v40_n10_p985_Doctorovich
work_keys_str_mv	AT doctorovichfabioariel performingorganicchemistrywithinorganiccompoundselectrophilicreactivityofselectednitrosylcomplexes AT disalvoflorencia performingorganicchemistrywithinorganiccompoundselectrophilicreactivityofselectednitrosylcomplexes
_version_	1840321936510418944

Performing organic chemistry with inorganic compounds: Electrophilic reactivity of selected nitrosyl complexes

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