Isotope Effects in Optical Rotation

A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approxim...

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Autor principal: Cohan, Norah Violeta
Publicado: 1966
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v88_n10_p2136_Cohan
http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00027863_v88_n10_p2136_Cohan
record_format dspace
spelling paper:paper_00027863_v88_n10_p2136_Cohan2023-06-08T14:22:57Z Isotope Effects in Optical Rotation Cohan, Norah Violeta A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approximation for infrared light. Detailed calculations are performed for the molecules CHDBrCl, CCl35Cl37BrF, and CHDTBr. Various summation rules are derived for the vibrational rotatory strengths. © 1966, American Chemical Society. All rights reserved. Fil:Cohan, N.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1966 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v88_n10_p2136_Cohan http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approximation for infrared light. Detailed calculations are performed for the molecules CHDBrCl, CCl35Cl37BrF, and CHDTBr. Various summation rules are derived for the vibrational rotatory strengths. © 1966, American Chemical Society. All rights reserved.
author Cohan, Norah Violeta
spellingShingle Cohan, Norah Violeta
Isotope Effects in Optical Rotation
author_facet Cohan, Norah Violeta
author_sort Cohan, Norah Violeta
title Isotope Effects in Optical Rotation
title_short Isotope Effects in Optical Rotation
title_full Isotope Effects in Optical Rotation
title_fullStr Isotope Effects in Optical Rotation
title_full_unstemmed Isotope Effects in Optical Rotation
title_sort isotope effects in optical rotation
publishDate 1966
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v88_n10_p2136_Cohan
http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan
work_keys_str_mv AT cohannorahvioleta isotopeeffectsinopticalrotation
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