Isotope Effects in Optical Rotation
A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approxim...
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1966
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v88_n10_p2136_Cohan http://hdl.handle.net/20.500.12110/paper_00027863_v88_n10_p2136_Cohan |
| Aporte de: |
| Sumario: | A general theory is derived for the optical rotatory power of molecules which exhibit this property only on account of isotopic substitution. The optical rotatory power is evaluated from the interaction between the nuclei and the radiation field only, and it is concluded that this is a good approximation for infrared light. Detailed calculations are performed for the molecules CHDBrCl, CCl35Cl37BrF, and CHDTBr. Various summation rules are derived for the vibrational rotatory strengths. © 1966, American Chemical Society. All rights reserved. |
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