Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol
The syntheses of 24‐methylidene[24‐14C]cholesterol (7a) and of 24‐methylidene[7‐3H]cholesterol (7b) from commercially available (20S)‐3‐oxopregn‐4‐ene‐20‐carbaldehyde (1) are described. The method also provides simple preparations of 3β‐acetoxy[24‐14C]chol‐5‐en‐24‐oic acid (4) and 24‐oxocholest‐5‐en...
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1990
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paper:paper_0018019X_v73_n8_p2097_Monteagudo2023-06-08T14:39:08Z Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol Monteagudo, Edith Sandra Burton, Gerardo Gros, Eduardo Gervasio The syntheses of 24‐methylidene[24‐14C]cholesterol (7a) and of 24‐methylidene[7‐3H]cholesterol (7b) from commercially available (20S)‐3‐oxopregn‐4‐ene‐20‐carbaldehyde (1) are described. The method also provides simple preparations of 3β‐acetoxy[24‐14C]chol‐5‐en‐24‐oic acid (4) and 24‐oxocholest‐5‐en‐3β‐yl acetate (6b). Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim Fil:Monteagudo, E.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1990 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v73_n8_p2097_Monteagudo http://hdl.handle.net/20.500.12110/paper_0018019X_v73_n8_p2097_Monteagudo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The syntheses of 24‐methylidene[24‐14C]cholesterol (7a) and of 24‐methylidene[7‐3H]cholesterol (7b) from commercially available (20S)‐3‐oxopregn‐4‐ene‐20‐carbaldehyde (1) are described. The method also provides simple preparations of 3β‐acetoxy[24‐14C]chol‐5‐en‐24‐oic acid (4) and 24‐oxocholest‐5‐en‐3β‐yl acetate (6b). Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim |
author |
Monteagudo, Edith Sandra Burton, Gerardo Gros, Eduardo Gervasio |
spellingShingle |
Monteagudo, Edith Sandra Burton, Gerardo Gros, Eduardo Gervasio Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
author_facet |
Monteagudo, Edith Sandra Burton, Gerardo Gros, Eduardo Gervasio |
author_sort |
Monteagudo, Edith Sandra |
title |
Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
title_short |
Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
title_full |
Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
title_fullStr |
Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
title_full_unstemmed |
Synthesis of 24‐Methylidene[24‐14C]‐ and 24‐Methylidene[7‐3H]cholesterol |
title_sort |
synthesis of 24‐methylidene[24‐14c]‐ and 24‐methylidene[7‐3h]cholesterol |
publishDate |
1990 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v73_n8_p2097_Monteagudo http://hdl.handle.net/20.500.12110/paper_0018019X_v73_n8_p2097_Monteagudo |
work_keys_str_mv |
AT monteagudoedithsandra synthesisof24methylidene2414cand24methylidene73hcholesterol AT burtongerardo synthesisof24methylidene2414cand24methylidene73hcholesterol AT groseduardogervasio synthesisof24methylidene2414cand24methylidene73hcholesterol |
_version_ |
1768542970123911168 |