Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate
In the title compound, C14H14N2OS 2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respect...
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_16005368_v68_n9_p_Dey |
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todo:paper_16005368_v68_n9_p_Dey2023-10-03T16:27:48Z Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate Dey, B.K. Suarez, S. Ganguly, B. Doctorovich, F. Roy, T.G. In the title compound, C14H14N2OS 2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C4N2S2), indicating a twisted conformation for the molecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C - H⋯π interactions involving the phenyl ring are observed. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_16005368_v68_n9_p_Dey |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
In the title compound, C14H14N2OS 2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C4N2S2), indicating a twisted conformation for the molecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C - H⋯π interactions involving the phenyl ring are observed. |
| format |
JOUR |
| author |
Dey, B.K. Suarez, S. Ganguly, B. Doctorovich, F. Roy, T.G. |
| spellingShingle |
Dey, B.K. Suarez, S. Ganguly, B. Doctorovich, F. Roy, T.G. Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| author_facet |
Dey, B.K. Suarez, S. Ganguly, B. Doctorovich, F. Roy, T.G. |
| author_sort |
Dey, B.K. |
| title |
Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| title_short |
Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| title_full |
Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| title_fullStr |
Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| title_full_unstemmed |
Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| title_sort |
benzyl 3-[(e)-(furan-2-yl)methylidene]-2-methyldithiocarbazate |
| url |
http://hdl.handle.net/20.500.12110/paper_16005368_v68_n9_p_Dey |
| work_keys_str_mv |
AT deybk benzyl3efuran2ylmethylidene2methyldithiocarbazate AT suarezs benzyl3efuran2ylmethylidene2methyldithiocarbazate AT gangulyb benzyl3efuran2ylmethylidene2methyldithiocarbazate AT doctorovichf benzyl3efuran2ylmethylidene2methyldithiocarbazate AT roytg benzyl3efuran2ylmethylidene2methyldithiocarbazate |
| _version_ |
1807314851303784448 |