On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles

Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first ti...

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Autores principales: Bonesi, Sergio Mauricio, Erra Balsells, Rosa
Publicado: 1997
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v34_n3_p891_Bonesi
http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_0022152X_v34_n3_p891_Bonesi
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spelling paper:paper_0022152X_v34_n3_p891_Bonesi2023-06-08T14:46:44Z On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles Bonesi, Sergio Mauricio Erra Balsells, Rosa Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared. Fil:Bonesi, S.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1997 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v34_n3_p891_Bonesi http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared.
author Bonesi, Sergio Mauricio
Erra Balsells, Rosa
spellingShingle Bonesi, Sergio Mauricio
Erra Balsells, Rosa
On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
author_facet Bonesi, Sergio Mauricio
Erra Balsells, Rosa
author_sort Bonesi, Sergio Mauricio
title On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_short On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_full On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_fullStr On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_full_unstemmed On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_sort on the synthesis and isolation of chlorocarbazoles obtained by chlorination of n-substituted carbazoles
publishDate 1997
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v34_n3_p891_Bonesi
http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
work_keys_str_mv AT bonesisergiomauricio onthesynthesisandisolationofchlorocarbazolesobtainedbychlorinationofnsubstitutedcarbazoles
AT errabalsellsrosa onthesynthesisandisolationofchlorocarbazolesobtainedbychlorinationofnsubstitutedcarbazoles
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