Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia

The fusion of the bicyclo[8.1.0]undecane system in the unique sesquiterpene diketone integrifolian-1,5-dione was found to be cis by X-ray analysis. A revised structure was derived for 'africanone' after reconsideration of the mass spectral data. The revised structure is based on a novel se...

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Detalles Bibliográficos
Autores principales:	Dartayet, Gustavo Horacio, Gros, Eduardo Gervasio
Publicado:	1991
Materias:	Lippia integrifolia sesquiterpene ketones stereochemistry structure Verbenaceae X-ray analysis.
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v30_n4_p1323_Catalan http://hdl.handle.net/20.500.12110/paper_00319422_v30_n4_p1323_Catalan
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00319422_v30_n4_p1323_Catalan
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spelling	paper:paper_00319422_v30_n4_p1323_Catalan2023-06-08T14:59:26Z Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia Dartayet, Gustavo Horacio Gros, Eduardo Gervasio Lippia integrifolia sesquiterpene ketones stereochemistry structure Verbenaceae X-ray analysis. The fusion of the bicyclo[8.1.0]undecane system in the unique sesquiterpene diketone integrifolian-1,5-dione was found to be cis by X-ray analysis. A revised structure was derived for 'africanone' after reconsideration of the mass spectral data. The revised structure is based on a novel sesquiterpene skeleton and was confirmed by a biomimetic synthesis from integrifolian-1,5-dione. © 1991. Fil:Dartayet, G.H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1991 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v30_n4_p1323_Catalan http://hdl.handle.net/20.500.12110/paper_00319422_v30_n4_p1323_Catalan
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Lippia integrifolia sesquiterpene ketones stereochemistry structure Verbenaceae X-ray analysis.
spellingShingle	Lippia integrifolia sesquiterpene ketones stereochemistry structure Verbenaceae X-ray analysis. Dartayet, Gustavo Horacio Gros, Eduardo Gervasio Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
topic_facet	Lippia integrifolia sesquiterpene ketones stereochemistry structure Verbenaceae X-ray analysis.
description	The fusion of the bicyclo[8.1.0]undecane system in the unique sesquiterpene diketone integrifolian-1,5-dione was found to be cis by X-ray analysis. A revised structure was derived for 'africanone' after reconsideration of the mass spectral data. The revised structure is based on a novel sesquiterpene skeleton and was confirmed by a biomimetic synthesis from integrifolian-1,5-dione. © 1991.
author	Dartayet, Gustavo Horacio Gros, Eduardo Gervasio
author_facet	Dartayet, Gustavo Horacio Gros, Eduardo Gervasio
author_sort	Dartayet, Gustavo Horacio
title	Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
title_short	Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
title_full	Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
title_fullStr	Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
title_full_unstemmed	Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia
title_sort	integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from lippia integrifolia
publishDate	1991
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v30_n4_p1323_Catalan http://hdl.handle.net/20.500.12110/paper_00319422_v30_n4_p1323_Catalan
work_keys_str_mv	AT dartayetgustavohoracio integrifolian15dioneandarevisedstructureforafricanonebiogeneticallyrelatedsesquiterpeneketonesfromlippiaintegrifolia AT groseduardogervasio integrifolian15dioneandarevisedstructureforafricanonebiogeneticallyrelatedsesquiterpeneketonesfromlippiaintegrifolia
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Integrifolian-1,5-dione and a revised structure for 'africanone', biogenetically related sesquiterpene ketones from Lippia integrifolia

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