Solubility in fluids close to their critical points

A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic c...

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Publicado: 1995
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v67_n4_p519_FernndezPrim
http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00334545_v67_n4_p519_FernndezPrim
record_format dspace
spelling paper:paper_00334545_v67_n4_p519_FernndezPrim2023-06-08T15:00:29Z Solubility in fluids close to their critical points A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic critical relations are a great help to evaluate data for volatile solutes, for solid solutes they help to separate contingent dependences of solubility from those which are essential. This analysis suggests there is no need to invoke the existence of critical clustering to explain the observed behaviour. © 1995 IUPAC 1995 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v67_n4_p519_FernndezPrim http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic critical relations are a great help to evaluate data for volatile solutes, for solid solutes they help to separate contingent dependences of solubility from those which are essential. This analysis suggests there is no need to invoke the existence of critical clustering to explain the observed behaviour. © 1995 IUPAC
title Solubility in fluids close to their critical points
spellingShingle Solubility in fluids close to their critical points
title_short Solubility in fluids close to their critical points
title_full Solubility in fluids close to their critical points
title_fullStr Solubility in fluids close to their critical points
title_full_unstemmed Solubility in fluids close to their critical points
title_sort solubility in fluids close to their critical points
publishDate 1995
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v67_n4_p519_FernndezPrim
http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
_version_ 1768542353895718912

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