The thermal decomposition of copper(II) nicotinate and isonicotinate

The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is...

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Autor principal: Sileo, Elsa Ester
Publicado: 1989
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406031_v138_n2_p233_Sileo
http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00406031_v138_n2_p233_Sileo
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spelling paper:paper_00406031_v138_n2_p233_Sileo2023-06-08T15:04:33Z The thermal decomposition of copper(II) nicotinate and isonicotinate Sileo, Elsa Ester The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is started by homolytic RC(O)O-Cu bond scission, which is equivalent to electron transfer from RC(O)O- to Cu(II). © 1989. Fil:Sileo, E.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1989 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406031_v138_n2_p233_Sileo http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is started by homolytic RC(O)O-Cu bond scission, which is equivalent to electron transfer from RC(O)O- to Cu(II). © 1989.
author Sileo, Elsa Ester
spellingShingle Sileo, Elsa Ester
The thermal decomposition of copper(II) nicotinate and isonicotinate
author_facet Sileo, Elsa Ester
author_sort Sileo, Elsa Ester
title The thermal decomposition of copper(II) nicotinate and isonicotinate
title_short The thermal decomposition of copper(II) nicotinate and isonicotinate
title_full The thermal decomposition of copper(II) nicotinate and isonicotinate
title_fullStr The thermal decomposition of copper(II) nicotinate and isonicotinate
title_full_unstemmed The thermal decomposition of copper(II) nicotinate and isonicotinate
title_sort thermal decomposition of copper(ii) nicotinate and isonicotinate
publishDate 1989
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406031_v138_n2_p233_Sileo
http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
work_keys_str_mv AT sileoelsaester thethermaldecompositionofcopperiinicotinateandisonicotinate
AT sileoelsaester thermaldecompositionofcopperiinicotinateandisonicotinate
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