Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate

The crystal structure of the title complex, [Ni(C3H4-N2)6]CO3.5H 2O, which is isostructural with the Cd, Co and Ru analogues, is built up from cationic and anionic sheets parallel to the basal plane of the hexagonal unit cell. The former contain the [Ni(C3H4N2)6]2+ cations and the latter the CO3 2-...

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Publicado: 1998
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n12_p1817_Povse
http://hdl.handle.net/20.500.12110/paper_01082701_v54_n12_p1817_Povse
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_01082701_v54_n12_p1817_Povse
record_format dspace
spelling paper:paper_01082701_v54_n12_p1817_Povse2023-06-08T15:10:38Z Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate The crystal structure of the title complex, [Ni(C3H4-N2)6]CO3.5H 2O, which is isostructural with the Cd, Co and Ru analogues, is built up from cationic and anionic sheets parallel to the basal plane of the hexagonal unit cell. The former contain the [Ni(C3H4N2)6]2+ cations and the latter the CO3 2- anions together with the hydration water molecules. These are disordered on both sides of the P63/m mirror plane, which thus exists in an average sense only. The sheets are linked by an extensive hydrogen-bonding system involving the non-coordinated NH imidazole groups, the hydration water molecules and the O atoms of the carbonate anions. The latter are acceptors of nine simultaneous strong hydrogen bonds. 1998 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n12_p1817_Povse http://hdl.handle.net/20.500.12110/paper_01082701_v54_n12_p1817_Povse
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The crystal structure of the title complex, [Ni(C3H4-N2)6]CO3.5H 2O, which is isostructural with the Cd, Co and Ru analogues, is built up from cationic and anionic sheets parallel to the basal plane of the hexagonal unit cell. The former contain the [Ni(C3H4N2)6]2+ cations and the latter the CO3 2- anions together with the hydration water molecules. These are disordered on both sides of the P63/m mirror plane, which thus exists in an average sense only. The sheets are linked by an extensive hydrogen-bonding system involving the non-coordinated NH imidazole groups, the hydration water molecules and the O atoms of the carbonate anions. The latter are acceptors of nine simultaneous strong hydrogen bonds.
title Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
spellingShingle Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
title_short Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
title_full Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
title_fullStr Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
title_full_unstemmed Hexakis(imidazole-N3)nickel(II) carbonate pentahydrate
title_sort hexakis(imidazole-n3)nickel(ii) carbonate pentahydrate
publishDate 1998
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n12_p1817_Povse
http://hdl.handle.net/20.500.12110/paper_01082701_v54_n12_p1817_Povse
_version_ 1768541932223463424

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