Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes

We have grown silver prisms and pentagonal bipyramids, induced by plasmon excitation on a colloidal solution under the irradiation of light emitting diodes of different colors. Two methods of synthesis of the seeds were tested and their growth evolution recorded, in order to analyze the effect of th...

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Autores principales: Scarpettini, Alberto F., Bragas, Andrea Verónica
Publicado: 2013
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v139_n1_p100_Bordenave
http://hdl.handle.net/20.500.12110/paper_02540584_v139_n1_p100_Bordenave
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spelling paper:paper_02540584_v139_n1_p100_Bordenave2023-06-08T15:21:56Z Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes Scarpettini, Alberto F. Bragas, Andrea Verónica Chemical synthesis Metals Nanostructures Optical properties Anisotropic nanoparticles Chemical environment Chemical synthesis Colloidal solutions Irradiation wavelength Methods of synthesis Photochemical synthesis Plasmon excitations Irradiation Metals Morphology Nanoparticles Nanostructures Optical properties Prisms Silver Light emitting diodes We have grown silver prisms and pentagonal bipyramids, induced by plasmon excitation on a colloidal solution under the irradiation of light emitting diodes of different colors. Two methods of synthesis of the seeds were tested and their growth evolution recorded, in order to analyze the effect of the chemical synthesis and the color of the irradiation on the morphology and size of the final product. We show that the conversion rate into anisotropic nanoparticles is determined by the chemical environment and the shift of the irradiation wavelength with respect to the plasmon resonance of the seeds. The conversion rate defines the final morphology of the nanoparticles, whereas the size of the nanoparticles is univocally determined by the wavelength of irradiation, irrespective of the method to prepare the seed solution. © 2013 Elsevier B.V. All rights reserved. Fil:Scarpettini, A.F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bragas, A.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2013 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v139_n1_p100_Bordenave http://hdl.handle.net/20.500.12110/paper_02540584_v139_n1_p100_Bordenave
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Chemical synthesis
Metals
Nanostructures
Optical properties
Anisotropic nanoparticles
Chemical environment
Chemical synthesis
Colloidal solutions
Irradiation wavelength
Methods of synthesis
Photochemical synthesis
Plasmon excitations
Irradiation
Metals
Morphology
Nanoparticles
Nanostructures
Optical properties
Prisms
Silver
Light emitting diodes
spellingShingle Chemical synthesis
Metals
Nanostructures
Optical properties
Anisotropic nanoparticles
Chemical environment
Chemical synthesis
Colloidal solutions
Irradiation wavelength
Methods of synthesis
Photochemical synthesis
Plasmon excitations
Irradiation
Metals
Morphology
Nanoparticles
Nanostructures
Optical properties
Prisms
Silver
Light emitting diodes
Scarpettini, Alberto F.
Bragas, Andrea Verónica
Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
topic_facet Chemical synthesis
Metals
Nanostructures
Optical properties
Anisotropic nanoparticles
Chemical environment
Chemical synthesis
Colloidal solutions
Irradiation wavelength
Methods of synthesis
Photochemical synthesis
Plasmon excitations
Irradiation
Metals
Morphology
Nanoparticles
Nanostructures
Optical properties
Prisms
Silver
Light emitting diodes
description We have grown silver prisms and pentagonal bipyramids, induced by plasmon excitation on a colloidal solution under the irradiation of light emitting diodes of different colors. Two methods of synthesis of the seeds were tested and their growth evolution recorded, in order to analyze the effect of the chemical synthesis and the color of the irradiation on the morphology and size of the final product. We show that the conversion rate into anisotropic nanoparticles is determined by the chemical environment and the shift of the irradiation wavelength with respect to the plasmon resonance of the seeds. The conversion rate defines the final morphology of the nanoparticles, whereas the size of the nanoparticles is univocally determined by the wavelength of irradiation, irrespective of the method to prepare the seed solution. © 2013 Elsevier B.V. All rights reserved.
author Scarpettini, Alberto F.
Bragas, Andrea Verónica
author_facet Scarpettini, Alberto F.
Bragas, Andrea Verónica
author_sort Scarpettini, Alberto F.
title Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
title_short Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
title_full Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
title_fullStr Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
title_full_unstemmed Plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
title_sort plasmon-induced photochemical synthesis of silver triangular prisms and pentagonal bipyramids by illumination with light emitting diodes
publishDate 2013
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v139_n1_p100_Bordenave
http://hdl.handle.net/20.500.12110/paper_02540584_v139_n1_p100_Bordenave
work_keys_str_mv AT scarpettinialbertof plasmoninducedphotochemicalsynthesisofsilvertriangularprismsandpentagonalbipyramidsbyilluminationwithlightemittingdiodes
AT bragasandreaveronica plasmoninducedphotochemicalsynthesisofsilvertriangularprismsandpentagonalbipyramidsbyilluminationwithlightemittingdiodes
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