Mesoporous ZnS thin films prepared by a nanocasting route

Mesoporous metal chalcogenides (e.g., ZnS, CuS, and derived mixed sulfide or selenides) show an extremely high potential in technological areas like catalysis, sensors, environmental protection, and photovoltaics. Although chemical bath deposition methods allow obtaining stable and porous metal chal...

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Autores principales:	Martinez Ricci, Maria Luz, Soler Illia, Galo Juan de Avila Arturo
Publicado:	2012
Materias:	mesoporous film nanocasting SILAR zinc sulfide Characterization techniques Chemical bath deposition methods Hard templates High potential Mesoporous Mesoporous films Mesoporous metal Mesoporous silica thin films Mesoporous thin films Mesostructured Nanocasting Ordered mesoporous Photovoltaics Porous metal Selective etching Selenides Successive ionic layer adsorption and reactions Sulfide thin films Synthetic methods Template removal ZnS thin films Adsorption Deposition Ionic liquids Mesoporous materials Phase change memory Selenium compounds Silica Sulfur compounds Thin films Vapor deposition Zinc Zinc sulfide Film preparation
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v24_n10_p1837_Fischereder http://hdl.handle.net/20.500.12110/paper_08974756_v24_n10_p1837_Fischereder
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_08974756_v24_n10_p1837_Fischereder
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spelling	paper:paper_08974756_v24_n10_p1837_Fischereder2023-06-08T15:49:19Z Mesoporous ZnS thin films prepared by a nanocasting route Martinez Ricci, Maria Luz Soler Illia, Galo Juan de Avila Arturo mesoporous film nanocasting SILAR zinc sulfide Characterization techniques Chemical bath deposition methods Hard templates High potential Mesoporous Mesoporous films Mesoporous metal Mesoporous silica thin films Mesoporous thin films Mesostructured Nanocasting Ordered mesoporous Photovoltaics Porous metal Selective etching Selenides SILAR Successive ionic layer adsorption and reactions Sulfide thin films Synthetic methods Template removal ZnS thin films Adsorption Deposition Ionic liquids Mesoporous materials Phase change memory Selenium compounds Silica Sulfur compounds Thin films Vapor deposition Zinc Zinc sulfide Film preparation Mesoporous metal chalcogenides (e.g., ZnS, CuS, and derived mixed sulfide or selenides) show an extremely high potential in technological areas like catalysis, sensors, environmental protection, and photovoltaics. Although chemical bath deposition methods allow obtaining stable and porous metal chalcogenide films under mild and simple conditions, the reproducible preparation of highly ordered mesoporous sulfide thin films has been challenging so far. Herein, we present a simple and efficient synthetic method to prepare ZnS mesoporous thin films using a combination of a nanocasting approach and a successive ionic layer adsorption and reaction (SILAR) process for the infiltration. A mesoporous silica thin film, prepared by evaporation induced self-assembly (EISA), serves as the hard exotemplate for the formation of the mesostructured zinc sulfide. After selective etching of the silica framework, a stable and porous ZnS thin film is obtained, which replicates the pore structure of the hard template. A thorough combination of characterization techniques is used to assess the exotemplating process as well as the template removal. © 2012 American Chemical Society. Fil:Martinez-Ricci, M.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v24_n10_p1837_Fischereder http://hdl.handle.net/20.500.12110/paper_08974756_v24_n10_p1837_Fischereder
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	mesoporous film nanocasting SILAR zinc sulfide Characterization techniques Chemical bath deposition methods Hard templates High potential Mesoporous Mesoporous films Mesoporous metal Mesoporous silica thin films Mesoporous thin films Mesostructured Nanocasting Ordered mesoporous Photovoltaics Porous metal Selective etching Selenides SILAR Successive ionic layer adsorption and reactions Sulfide thin films Synthetic methods Template removal ZnS thin films Adsorption Deposition Ionic liquids Mesoporous materials Phase change memory Selenium compounds Silica Sulfur compounds Thin films Vapor deposition Zinc Zinc sulfide Film preparation
spellingShingle	mesoporous film nanocasting SILAR zinc sulfide Characterization techniques Chemical bath deposition methods Hard templates High potential Mesoporous Mesoporous films Mesoporous metal Mesoporous silica thin films Mesoporous thin films Mesostructured Nanocasting Ordered mesoporous Photovoltaics Porous metal Selective etching Selenides SILAR Successive ionic layer adsorption and reactions Sulfide thin films Synthetic methods Template removal ZnS thin films Adsorption Deposition Ionic liquids Mesoporous materials Phase change memory Selenium compounds Silica Sulfur compounds Thin films Vapor deposition Zinc Zinc sulfide Film preparation Martinez Ricci, Maria Luz Soler Illia, Galo Juan de Avila Arturo Mesoporous ZnS thin films prepared by a nanocasting route
topic_facet	mesoporous film nanocasting SILAR zinc sulfide Characterization techniques Chemical bath deposition methods Hard templates High potential Mesoporous Mesoporous films Mesoporous metal Mesoporous silica thin films Mesoporous thin films Mesostructured Nanocasting Ordered mesoporous Photovoltaics Porous metal Selective etching Selenides SILAR Successive ionic layer adsorption and reactions Sulfide thin films Synthetic methods Template removal ZnS thin films Adsorption Deposition Ionic liquids Mesoporous materials Phase change memory Selenium compounds Silica Sulfur compounds Thin films Vapor deposition Zinc Zinc sulfide Film preparation
description	Mesoporous metal chalcogenides (e.g., ZnS, CuS, and derived mixed sulfide or selenides) show an extremely high potential in technological areas like catalysis, sensors, environmental protection, and photovoltaics. Although chemical bath deposition methods allow obtaining stable and porous metal chalcogenide films under mild and simple conditions, the reproducible preparation of highly ordered mesoporous sulfide thin films has been challenging so far. Herein, we present a simple and efficient synthetic method to prepare ZnS mesoporous thin films using a combination of a nanocasting approach and a successive ionic layer adsorption and reaction (SILAR) process for the infiltration. A mesoporous silica thin film, prepared by evaporation induced self-assembly (EISA), serves as the hard exotemplate for the formation of the mesostructured zinc sulfide. After selective etching of the silica framework, a stable and porous ZnS thin film is obtained, which replicates the pore structure of the hard template. A thorough combination of characterization techniques is used to assess the exotemplating process as well as the template removal. © 2012 American Chemical Society.
author	Martinez Ricci, Maria Luz Soler Illia, Galo Juan de Avila Arturo
author_facet	Martinez Ricci, Maria Luz Soler Illia, Galo Juan de Avila Arturo
author_sort	Martinez Ricci, Maria Luz
title	Mesoporous ZnS thin films prepared by a nanocasting route
title_short	Mesoporous ZnS thin films prepared by a nanocasting route
title_full	Mesoporous ZnS thin films prepared by a nanocasting route
title_fullStr	Mesoporous ZnS thin films prepared by a nanocasting route
title_full_unstemmed	Mesoporous ZnS thin films prepared by a nanocasting route
title_sort	mesoporous zns thin films prepared by a nanocasting route
publishDate	2012
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v24_n10_p1837_Fischereder http://hdl.handle.net/20.500.12110/paper_08974756_v24_n10_p1837_Fischereder
work_keys_str_mv	AT martinezriccimarialuz mesoporousznsthinfilmspreparedbyananocastingroute AT solerilliagalojuandeavilaarturo mesoporousznsthinfilmspreparedbyananocastingroute
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Mesoporous ZnS thin films prepared by a nanocasting route

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