Hybridization functions of intermetallic Ce compounds with group VI elements

Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems...

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Guardado en:
Detalles Bibliográficos
Publicado: 2006
Materias:
Crystal fields
Highly correlated systems
p-electron
Band structure
Electrons
Fermi level
Intermetallics
Conduction band
Density of states
Monochalcogenides
Cerium compounds
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v384_n1-2_p202_RouraBas
http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_09214526_v384_n1-2_p202_RouraBas
record_format dspace
spelling paper:paper_09214526_v384_n1-2_p202_RouraBas2023-06-08T15:50:28Z Hybridization functions of intermetallic Ce compounds with group VI elements Crystal fields Highly correlated systems p-electron Band structure Electrons Fermi level Intermetallics Conduction band Density of states Monochalcogenides Cerium compounds Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems to be responsible for the unusual properties, in particular the magnetic ones which show great chemical sensitivity. As compared to the monopnictides, the monochalcogenides have an additional anion p-electron which shifts the Fermi energy into the p-region of the Cerium 5d-derived density of states, and which should affect the hybridization function of the electrons in the conduction band. In this contribution we analyze the 4f-hybridization function and the crystal-field splittings of the compounds under study. © 2006 Elsevier B.V. All rights reserved. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v384_n1-2_p202_RouraBas http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Crystal fields
Highly correlated systems
p-electron
Band structure
Electrons
Fermi level
Intermetallics
Conduction band
Density of states
Monochalcogenides
Cerium compounds
spellingShingle Crystal fields
Highly correlated systems
p-electron
Band structure
Electrons
Fermi level
Intermetallics
Conduction band
Density of states
Monochalcogenides
Cerium compounds
Hybridization functions of intermetallic Ce compounds with group VI elements
topic_facet Crystal fields
Highly correlated systems
p-electron
Band structure
Electrons
Fermi level
Intermetallics
Conduction band
Density of states
Monochalcogenides
Cerium compounds
description Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems to be responsible for the unusual properties, in particular the magnetic ones which show great chemical sensitivity. As compared to the monopnictides, the monochalcogenides have an additional anion p-electron which shifts the Fermi energy into the p-region of the Cerium 5d-derived density of states, and which should affect the hybridization function of the electrons in the conduction band. In this contribution we analyze the 4f-hybridization function and the crystal-field splittings of the compounds under study. © 2006 Elsevier B.V. All rights reserved.
title Hybridization functions of intermetallic Ce compounds with group VI elements
title_short Hybridization functions of intermetallic Ce compounds with group VI elements
title_full Hybridization functions of intermetallic Ce compounds with group VI elements
title_fullStr Hybridization functions of intermetallic Ce compounds with group VI elements
title_full_unstemmed Hybridization functions of intermetallic Ce compounds with group VI elements
title_sort hybridization functions of intermetallic ce compounds with group vi elements
publishDate 2006
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v384_n1-2_p202_RouraBas
http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas
_version_ 1768543042096070656

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