Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties
Mesoporous Thin Films (MTF) can be created by combining sol-gel synthesis, template self-assembly and chemical surface modification. A wide palette of inorganic (oxides, phosphates, carbon-based, etc.) and hybrid organic-inorganic frameworks with a variety of composition, pore sizes, and nanoscale,...
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2011
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09280707_v57_n3_p299_SolerIllia http://hdl.handle.net/20.500.12110/paper_09280707_v57_n3_p299_SolerIllia |
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paper:paper_09280707_v57_n3_p299_SolerIllia2025-07-30T18:28:21Z Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties Soler Illia, Galo Juan de Avila Arturo Angelomé, Paula C. Zelcer, Andrés Bellino, Martín G. Functional materials Mesoporous films Mesoporous hybrids Nanochemistry Thin films Biological functions Building blockes Carbon-based Chemical surface modification Complex structure Controlled environment Different length scale Mesoporous films Mesoporous hybrids Mesoporous thin films Mesoscopics Modular synthesis Monodisperse Multiscales Nano chemistry Nano scale Nano-cavities Nano-confined systems Nanocomposite thin films Organic functional groups Organic-inorganic Pore surface Pore system Pore volume Selected examples Sol-gel synthesis Surface feature Chemical modification Chemical properties Functional groups Functional materials Gels Nanocomposite films Nanocomposites Optical transfer function Pore size Sol-gel process Sol-gels Sols Surfaces Thin films Mesoporous materials Mesoporous Thin Films (MTF) can be created by combining sol-gel synthesis, template self-assembly and chemical surface modification. A wide palette of inorganic (oxides, phosphates, carbon-based, etc.) and hybrid organic-inorganic frameworks with a variety of composition, pore sizes, and nanoscale, organic or biological functions located in the inorganic skeleton, pore surface or pore interior can be obtained. The properties of the functional pore systems are tuned by the pore size and geometry, wall composition and surface features. These MTF with interesting electronic and optical controlled features are indeed a "nanofacility". Well-defined monodisperse sized pores also act as nanoreactors, or nanocavities with controlled environment and behaviour. In the last years, the production of accessible MTF, in which either the pore surface or pore volume can be modified by organic functional groups or nanoparticles has been thoroughly explored. Each highly controlled MTF originated from a reproducible and modular synthesis is in itself a building block for more complex structures, presenting order at different length scales (molecular, mesoscopic, macroscopic), and novel properties derived thereof. Selected examples of optical and chemical behaviour of these multiscale materials are presented to illustrate these points. © 2010 Springer Science+Business Media, LLC. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Angelomé, P.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Zelcer, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bellino, M.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09280707_v57_n3_p299_SolerIllia http://hdl.handle.net/20.500.12110/paper_09280707_v57_n3_p299_SolerIllia |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Functional materials Mesoporous films Mesoporous hybrids Nanochemistry Thin films Biological functions Building blockes Carbon-based Chemical surface modification Complex structure Controlled environment Different length scale Mesoporous films Mesoporous hybrids Mesoporous thin films Mesoscopics Modular synthesis Monodisperse Multiscales Nano chemistry Nano scale Nano-cavities Nano-confined systems Nanocomposite thin films Organic functional groups Organic-inorganic Pore surface Pore system Pore volume Selected examples Sol-gel synthesis Surface feature Chemical modification Chemical properties Functional groups Functional materials Gels Nanocomposite films Nanocomposites Optical transfer function Pore size Sol-gel process Sol-gels Sols Surfaces Thin films Mesoporous materials |
| spellingShingle |
Functional materials Mesoporous films Mesoporous hybrids Nanochemistry Thin films Biological functions Building blockes Carbon-based Chemical surface modification Complex structure Controlled environment Different length scale Mesoporous films Mesoporous hybrids Mesoporous thin films Mesoscopics Modular synthesis Monodisperse Multiscales Nano chemistry Nano scale Nano-cavities Nano-confined systems Nanocomposite thin films Organic functional groups Organic-inorganic Pore surface Pore system Pore volume Selected examples Sol-gel synthesis Surface feature Chemical modification Chemical properties Functional groups Functional materials Gels Nanocomposite films Nanocomposites Optical transfer function Pore size Sol-gel process Sol-gels Sols Surfaces Thin films Mesoporous materials Soler Illia, Galo Juan de Avila Arturo Angelomé, Paula C. Zelcer, Andrés Bellino, Martín G. Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| topic_facet |
Functional materials Mesoporous films Mesoporous hybrids Nanochemistry Thin films Biological functions Building blockes Carbon-based Chemical surface modification Complex structure Controlled environment Different length scale Mesoporous films Mesoporous hybrids Mesoporous thin films Mesoscopics Modular synthesis Monodisperse Multiscales Nano chemistry Nano scale Nano-cavities Nano-confined systems Nanocomposite thin films Organic functional groups Organic-inorganic Pore surface Pore system Pore volume Selected examples Sol-gel synthesis Surface feature Chemical modification Chemical properties Functional groups Functional materials Gels Nanocomposite films Nanocomposites Optical transfer function Pore size Sol-gel process Sol-gels Sols Surfaces Thin films Mesoporous materials |
| description |
Mesoporous Thin Films (MTF) can be created by combining sol-gel synthesis, template self-assembly and chemical surface modification. A wide palette of inorganic (oxides, phosphates, carbon-based, etc.) and hybrid organic-inorganic frameworks with a variety of composition, pore sizes, and nanoscale, organic or biological functions located in the inorganic skeleton, pore surface or pore interior can be obtained. The properties of the functional pore systems are tuned by the pore size and geometry, wall composition and surface features. These MTF with interesting electronic and optical controlled features are indeed a "nanofacility". Well-defined monodisperse sized pores also act as nanoreactors, or nanocavities with controlled environment and behaviour. In the last years, the production of accessible MTF, in which either the pore surface or pore volume can be modified by organic functional groups or nanoparticles has been thoroughly explored. Each highly controlled MTF originated from a reproducible and modular synthesis is in itself a building block for more complex structures, presenting order at different length scales (molecular, mesoscopic, macroscopic), and novel properties derived thereof. Selected examples of optical and chemical behaviour of these multiscale materials are presented to illustrate these points. © 2010 Springer Science+Business Media, LLC. |
| author |
Soler Illia, Galo Juan de Avila Arturo Angelomé, Paula C. Zelcer, Andrés Bellino, Martín G. |
| author_facet |
Soler Illia, Galo Juan de Avila Arturo Angelomé, Paula C. Zelcer, Andrés Bellino, Martín G. |
| author_sort |
Soler Illia, Galo Juan de Avila Arturo |
| title |
Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| title_short |
Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| title_full |
Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| title_fullStr |
Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| title_full_unstemmed |
Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| title_sort |
mesoporous hybrid and nanocomposite thin films. a sol-gel toolbox to create nanoconfined systems with localized chemical properties |
| publishDate |
2011 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09280707_v57_n3_p299_SolerIllia http://hdl.handle.net/20.500.12110/paper_09280707_v57_n3_p299_SolerIllia |
| work_keys_str_mv |
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| _version_ |
1840328153994625024 |